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Title: Robust superconductivity with large upper critical field in Nb{sub 2}PdS{sub 5}

We report synthesis, structural details, and complete superconducting characterization of very recently discovered [Q. Zhang, Sci. Rep. 3, 1446 (2013)] Nb{sub 2}PdS{sub 5} new superconductor. The synthesized compound is crystallized in monoclinic structure with C2/m (#12) space group. Bulk superconductivity is seen in both ac/dc magnetic susceptibility and electrical resistivity measurements with superconducting transition temperature (T{sub c}) at 6 K. The upper critical field (H{sub c2}) being estimated from high field magneto-transport [ρ(T)H] measurements is above 240 kOe. The estimated H{sub c2}(0) is clearly above the Pauli paramagnetic limit of ∼1.84T{sub c}. Heat capacity (C{sub p}) measurements show clear transition with well defined peak at T{sub c}, but with lower jump than as expected for a Bardeen–Cooper–Schrieffer type superconductor. The Sommerfeld constant (γ) and Debye temperature (Θ{sub D}) as determined from low temperature fitting of C{sub P}(T) data are 32 mJ/mole-K{sup 2} and 263 K, respectively. Hall coefficients and resistivity in conjugation with electronic heat capacity indicates multiple gap superconductivity signatures in Nb{sub 2}PdS{sub 5}. We also studied the impact of hydrostatic pressure (0–1.97 Gpa) on superconductivity of Nb{sub 2}PdS{sub 5} and found nearly no change in T{sub c} for the given pressure range.
Authors:
; ; ; ;  [1]
  1. Quantum Phenomena and Applications Division, National Physical Laboratory (CSIR), Dr. K. S. Krishnan Road, New Delhi-110012 (India)
Publication Date:
OSTI Identifier:
22304255
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Applied Physics; Journal Volume: 115; Journal Issue: 21; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; BCS THEORY; CRITICAL FIELD; DEBYE TEMPERATURE; MAGNETIC SUSCEPTIBILITY; MONOCLINIC LATTICES; NIOBIUM COMPOUNDS; PALLADIUM COMPOUNDS; PARAMAGNETISM; PRESSURE RANGE GIGA PA; SOMMERFELD CONSTANT; SPACE GROUPS; SPECIFIC HEAT; SULFUR COMPOUNDS; SUPERCONDUCTIVITY; SUPERCONDUCTORS; SYNTHESIS; TERNARY ALLOY SYSTEMS; TRANSITION TEMPERATURE