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Title: New porous titanium–niobium oxide for photocatalytic degradation of bromocresol green dye in aqueous solution

Graphical abstract: The photocatalytic activity of different porous titanium–niobium oxides was evaluated toward degradation of bromocresol green (BG) under UV light. A better catalytic activity was observed for all samples at lower pH. Catalysts have a stronger ability for degradation of BG in acid media than in alkaline media. - Highlights: • Different highly structured titanium–niobium oxides have been prepared using improved methods of synthesis. • Photo-degradation of bromocresol green dye (BG) with nanostructure titanium–niobium oxide catalysts was carried out under UV light. • The photo-catalytic activity of all catalysts was higher in lower pH. • Titanium–niobium oxide catalysts are considerably stable and reusable. - Abstract: In this study, high surface area semiconductors, non porous and porous titanium–niobium oxides derived from KTiNbO{sub 5} were synthesized, characterized and developed for their utility as photocatalysts for decontamination with sunlight. These materials were then used in the photocatalytic degradation of bromocresol green dye (BG) in aqueous solution using UV light and their catalytic activities were evaluated at various pHs. For all catalysts, the photocatalytic degradation of BG was most efficient in acidic solutions. Results show that the new porous oxides have large porous and high surface areas and high catalytic activity. A topotacticmore » dehydration treatment greatly improves catalyst performance at various pHs. Stability and long term activity of porous materials (topo and non-topo) in photocatalysis reactions was also tested. These results suggest that the new materials can be used to efficiently purify contaminated water.« less
Authors:
 [1] ; ;  [1] ;  [2] ;  [1]
  1. Materials Research and Technology Institute (MRTI), University of Texas at El Paso, 500W. University Ave., El Paso, TX 79968 (United States)
  2. Department of Chemistry, University of Texas at El Paso, 500W. University Ave., El Paso, TX 79968 (United States)
Publication Date:
OSTI Identifier:
22285125
Resource Type:
Journal Article
Resource Relation:
Journal Name: Materials Research Bulletin; Journal Volume: 48; Journal Issue: 10; Other Information: Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; AQUEOUS SOLUTIONS; CATALYSTS; DEHYDRATION; DYES; NANOSTRUCTURES; OXIDES; PHOTOCATALYSIS; POROUS MATERIALS; SEMICONDUCTOR MATERIALS; SYNTHESIS; TRIOCTYLPHOSPHINE OXIDE; ULTRAVIOLET RADIATION