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Title: Intracavity quartz-enhanced photoacoustic sensor

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.4867268· OSTI ID:22283061
; ; ;  [1]; ; ;  [2];  [3];  [4]
  1. CNR-INO UOS Sesto Fiorentino and LENS, via Carrara 1, 50019 Sesto Fiorentino FI (Italy)
  2. CNR-IFN UOS Bari and Dipartimento Interateneo di Fisica, Università degli Studi di Bari e Politecnico di Bari, via Amendola 173, 70126 Bari BA (Italy)
  3. Development Bureau Laser Device R and D Group, Hamamatsu Photonics KK, Shizuoka 434-8601 (Japan)
  4. Central Research Laboratories, Hamamatsu Photonics KK, Shizuoka 434-8601 (Japan)

We report on a spectroscopic technique named intracavity quartz-enhanced photoacoustic spectroscopy (I-QEPAS) employed for sensitive trace-gas detection in the mid-infrared spectral region. It is based on a combination of QEPAS with a buildup optical cavity. The sensor includes a distributed feedback quantum cascade laser emitting at 4.33 μm. We achieved a laser optical power buildup factor of ∼500, which corresponds to an intracavity laser power of ∼0.75 W. CO{sub 2} has been selected as the target molecule for the I-QEPAS demonstration. We achieved a detection sensitivity of 300 parts per trillion for 4 s integration time, corresponding to a noise equivalent absorption coefficient of 1.4 × 10{sup −8} cm{sup −1} and a normalized noise-equivalent absorption of 3.2 × 10{sup −10} W cm{sup −1} Hz{sup −1/2}.

OSTI ID:
22283061
Journal Information:
Applied Physics Letters, Vol. 104, Issue 9; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0003-6951
Country of Publication:
United States
Language:
English