skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Asymmetric twins in rhombohedral boron carbide

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.4861182· OSTI ID:22275800
; ; ; ;  [1];  [1]
  1. WPI Advanced Institute for Materials Research, Tohoku University, Sendai 980-8577 (Japan)

Superhard materials consisting of light elements have recently received considerable attention because of their ultrahigh specific strength for a wide range of applications as structural and functional materials. However, the failure mechanisms of these materials subjected to high stresses and dynamic loading remain to be poorly known. We report asymmetric twins in a complex compound, boron carbide (B{sub 4}C), characterized by spherical-aberration-corrected transmission electron microscopy. The atomic structure of boron-rich icosahedra at rhombohedral vertices and cross-linked carbon-rich atomic chains can be clearly visualized, which reveals unusual asymmetric twins with detectable strains along the twin interfaces. This study offers atomic insights into the structure of twins in a complex material and has important implications in understanding the planar defect-related failure of superhard materials under high stresses and shock loading.

OSTI ID:
22275800
Journal Information:
Applied Physics Letters, Vol. 104, Issue 2; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0003-6951
Country of Publication:
United States
Language:
English

Similar Records

Vapor deposition of binary boron--carbon phases at substrate temperatures of 900 to 1800$sup 0$C. II. Rhombohedral boron carbide
Journal Article · Fri Mar 01 00:00:00 EDT 1974 · J. Less-Common Metals, v. 35, no. 1, pp. 131-145 · OSTI ID:22275800

Activating dislocation mediated plasticity in boron carbide through Al-doping
Journal Article · Fri Oct 07 00:00:00 EDT 2022 · Acta Materialia · OSTI ID:22275800

Boron carbide structure by Raman spectroscopy
Journal Article · Fri Sep 15 00:00:00 EDT 1989 · Physical Review (Section) B: Condensed Matter; (USA) · OSTI ID:22275800