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Title: Crystal structure and electric properties of the organic–inorganic hybrid: [(CH{sub 2}){sub 6}(NH{sub 3}){sub 2}]ZnCl{sub 4}

The new organic-inorganic hybrid [(CH{sub 2}){sub 6}(NH{sub 3}){sub 2}]ZnCl{sub 4}, M{sub r}=325.406 crystallized in a triclinic, P1¯, a=7.2816 (5) Å, b=10.0996 (7) Å, c=10.0972 (7) Å, α=74.368 (4)°, β=88.046 (4)°, γ=85.974 (3)°, V=713.24 (9) Å{sup 3} and Z=2, D{sub x}=1.486 Mg m{sup −3}. Differential thermal scanning and x-ray powder diffraction, permittivity and ac conductivity indicated three phase transitions. Conduction takes place via correlated barrier hopping. - Graphical abstract: Display Omitted.
Authors:
;
Publication Date:
OSTI Identifier:
22274179
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 209; Other Information: Copyright (c) 2013 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; AMMONIA; CHLORIDES; CRYSTAL STRUCTURE; DIELECTRIC MATERIALS; HYBRIDIZATION; PERMITTIVITY; PHASE TRANSFORMATIONS; X RADIATION; X-RAY DIFFRACTION