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Title: Optical and phonon properties of ZnO:CuO mixed nanocomposite

Optical and phonon properties of ZnO:CuO nanocrystals which are prepared through sol-gel method are reported here. From X-ray diffraction studies, observed that Cu doping replaces the Zn and also forms secondary phase. Optical absorption spectral studies shows that the exciton and plasmon related bands of ZnO and CuO phase, respectively. Fluorescence studies of the prepared samples shows that green emission from ZnO is completely depleted and the same is attributed to CuO Plasmon. Raman spectral studies reveal that secondary phase (impurity) induced profile changes in 1LO and E{sub 2High} modes. Asymmetry in peak shape is analyzed using Fano profile with the combination of Lorentzian profile. Moreover, the monotonic increase of Fano factor and full width at half maxima is hopefully attributed to the continuum arises by the plasmons of Cu-O phase in ZnO nanosystem.
Authors:
;  [1]
  1. Department of Physics, National Institute of Technology, Tiruchirappalli 620 015 (India)
Publication Date:
OSTI Identifier:
22273570
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Applied Physics; Journal Volume: 115; Journal Issue: 15; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 77 NANOSCIENCE AND NANOTECHNOLOGY; COMPOSITE MATERIALS; COPPER OXIDES; CRYSTALS; FANO FACTOR; FLUORESCENCE; NANOSTRUCTURES; PHONONS; PLASMONS; SOL-GEL PROCESS; X-RAY DIFFRACTION; ZINC OXIDES