skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: EPR and optical absorption by Cu{sup 2+} ions in ZnO−Li{sub 2}O−Na{sub 2}O−K{sub 2}O−B{sub 2}O{sub 3} glasses

Abstract

Electron Paramagnetic Resonance (EPR) studies at room temperature in the x-band frequencies on xZnO−10Li{sub 2}O−10Na{sub 2}O−10K{sub 2}O−(69−x)B{sub 2}O{sub 3}−1CuO (x=0,2,4,6 and 8 mole%) glass systems were reported. The non-linear variation of spin-Hamiltonian parameters with ZnO content indicated the change in the ligand field strength around Cu{sup 2+} ions in the host glass. The ground state of Cu{sup 2+} ions in the glass is designated as d{sub x{sup 2}−y{sup 2}} orbital ({sup 2}B{sub 1g}) while the observed symmetry around it is tetragonally distorted octahedral. The molecular orbital coefficients α{sup 2}, β{sup 2} and β{sub 1}{sup 2} are evaluated for Cu{sup 2+} doped samples. The non-linear variation in the values of parameters indicated mixed alkali effect in the glasses.

Authors:
; ;  [1];  [2]
  1. Department of Physics, Osmania University, Hyderabad-500007 (India)
  2. Department of Physics, Vasavi college of Engineering, Hyderabad-500031 (India)
Publication Date:
OSTI Identifier:
22271041
Resource Type:
Journal Article
Journal Name:
AIP Conference Proceedings
Additional Journal Information:
Journal Volume: 1591; Journal Issue: 1; Conference: 58. DAE solid state physics symposium 2013, Patiala, Punjab (India), 17-21 Dec 2013; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0094-243X
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; BORON OXIDES; CONCENTRATION RATIO; COPPER IONS; DOPED MATERIALS; ELECTRON SPIN RESONANCE; GLASS; GROUND STATES; HAMILTONIANS; LIGANDS; LITHIUM OXIDES; MOLECULAR ORBITAL METHOD; NONLINEAR PROBLEMS; POTASSIUM OXIDES; SODIUM OXIDES; SPIN; TEMPERATURE RANGE 0273-0400 K; ZINC OXIDES

Citation Formats

Hameed, Abdul, Shareefuddin, Md., Chary, M. Narasimha, and Ramadevudu, G. EPR and optical absorption by Cu{sup 2+} ions in ZnO−Li{sub 2}O−Na{sub 2}O−K{sub 2}O−B{sub 2}O{sub 3} glasses. United States: N. p., 2014. Web. doi:10.1063/1.4872775.
Hameed, Abdul, Shareefuddin, Md., Chary, M. Narasimha, & Ramadevudu, G. EPR and optical absorption by Cu{sup 2+} ions in ZnO−Li{sub 2}O−Na{sub 2}O−K{sub 2}O−B{sub 2}O{sub 3} glasses. United States. https://doi.org/10.1063/1.4872775
Hameed, Abdul, Shareefuddin, Md., Chary, M. Narasimha, and Ramadevudu, G. 2014. "EPR and optical absorption by Cu{sup 2+} ions in ZnO−Li{sub 2}O−Na{sub 2}O−K{sub 2}O−B{sub 2}O{sub 3} glasses". United States. https://doi.org/10.1063/1.4872775.
@article{osti_22271041,
title = {EPR and optical absorption by Cu{sup 2+} ions in ZnO−Li{sub 2}O−Na{sub 2}O−K{sub 2}O−B{sub 2}O{sub 3} glasses},
author = {Hameed, Abdul and Shareefuddin, Md. and Chary, M. Narasimha and Ramadevudu, G.},
abstractNote = {Electron Paramagnetic Resonance (EPR) studies at room temperature in the x-band frequencies on xZnO−10Li{sub 2}O−10Na{sub 2}O−10K{sub 2}O−(69−x)B{sub 2}O{sub 3}−1CuO (x=0,2,4,6 and 8 mole%) glass systems were reported. The non-linear variation of spin-Hamiltonian parameters with ZnO content indicated the change in the ligand field strength around Cu{sup 2+} ions in the host glass. The ground state of Cu{sup 2+} ions in the glass is designated as d{sub x{sup 2}−y{sup 2}} orbital ({sup 2}B{sub 1g}) while the observed symmetry around it is tetragonally distorted octahedral. The molecular orbital coefficients α{sup 2}, β{sup 2} and β{sub 1}{sup 2} are evaluated for Cu{sup 2+} doped samples. The non-linear variation in the values of parameters indicated mixed alkali effect in the glasses.},
doi = {10.1063/1.4872775},
url = {https://www.osti.gov/biblio/22271041}, journal = {AIP Conference Proceedings},
issn = {0094-243X},
number = 1,
volume = 1591,
place = {United States},
year = {Thu Apr 24 00:00:00 EDT 2014},
month = {Thu Apr 24 00:00:00 EDT 2014}
}