Effects of pre-annealing on the uni- and bi-axial stretching behavior of poly(ethylene naphthalate) films
- Dept. Organic and Polymeric Materials, Tokyo Institute of Technology (Japan)
Effect of pre-annealing on stress and birefringence behavior of poly(ethylene naphthalate) (PEN) films during stretching and relaxation processes was investigated. Amorphous and non-oriented PEN films were pre-annealed under the conditions of different temperatures and periods. The pre-annealed films were stretched uniaxially or equi-biaxially and then relaxed at fixed length. It was found that pre-annealing did not cause any notable change for the initial behavior of refractive indices variation, whereas the behaviors after necking were significantly affected. Through the comparison between in-plane and out-of-plane birefringence and the analysis of wide-angle x-ray diffraction patterns of drawn films of both stretching modes, it was confirmed that the orientation of naphthalene ring in the film plane was enhanced by pre-annealing.
- OSTI ID:
- 22270996
- Journal Information:
- AIP Conference Proceedings, Vol. 1593, Issue 1; Conference: PPS-29: 29. international conference of the Polymer Processing Society, Nuremberg (Germany), 15-19 Jul 2013; Other Information: (c) 2014 American Institute of Physics; Country of input: International Atomic Energy Agency (IAEA); ISSN 0094-243X
- Country of Publication:
- United States
- Language:
- English
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