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Title: Preparation of polyaniline/sodium alanate hybrid using a spray-drying process

Nowadays, hydrogen is highly interesting as an energy source, in particular in the automotive field. In fact, hydrogen is attractive as a fuel because it prevents air pollution and greenhouse emissions. One of the main problems with the utilization of hydrogen as a fuel is its on-board storage. The purpouse of this work was to develop a new hybrid material consisting of a polyaniline matrix with sodium alanate (NaAlH{sub 4}) using a spray-drying process. The polyaniline used for this experiment was synthesized by following a well-established method for the synthesis of the emeraldine base form of polyaniline using dodecylbenzenesulfonic acid as dopant. Micro particles of polyaniline/sodium alanate hybrids with 30 and 50 wt% of sodium alanate were prepared by using a spray-drying technique. Dilute solutions of polyaniline/sodium alanate were first prepared, 10g of the solid materials were mixed with 350 ml of toluene under stirring at room temperature for 24h and the solutions were dried using spray-dryer (Büchi, Switzerland) with 115°C of an inlet temperature. The hybrids were analyzed by differential scanning calorimetry, FT-IR and scanning electron microscopy (SEM). The addition of sodium alanate decreased the glass transition temperature of the hybrids when compared to neat polyaniline. FT-IR spectrum analysismore » was performed to identify the bonding environment of the synthesized material and was observed that simply physically mixture occurred between polyaniline and sodium alanate. The SEM images of the hybrids showed the formation of microspheres with sodium alanate dispersed in the polymer matrix.« less
Authors:
; ;  [1]
  1. Dep. de Engenharia de Materiais, Federal University of São Carlos (Brazil)
Publication Date:
OSTI Identifier:
22270983
Resource Type:
Journal Article
Resource Relation:
Journal Name: AIP Conference Proceedings; Journal Volume: 1593; Journal Issue: 1; Conference: PPS-29: 29. international conference of the Polymer Processing Society, Nuremberg (Germany), 15-19 Jul 2013; Other Information: (c) 2014 American Institute of Physics; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 08 HYDROGEN; ALUMINIUM HYDRIDES; ANILINE; CALORIMETRY; COMPARATIVE EVALUATIONS; DIFFERENTIAL THERMAL ANALYSIS; HYDROGEN; HYDROGEN STORAGE; INFRARED SPECTRA; MATRIX MATERIALS; ORGANIC POLYMERS; SCANNING ELECTRON MICROSCOPY; SODIUM COMPOUNDS; SPRAY DRYING; TEMPERATURE RANGE 0273-0400 K; TOLUENE; TRANSITION TEMPERATURE