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Title: LINE PARAMETERS OF THE 782 nm BAND OF CO{sub 2}

The 782 nm band of CO{sub 2}, in a transparent window of Earth's atmosphere, was the first CO{sub 2} band observed 80 yr ago in the spectra of Venus. The band is very weak and therefore not saturated by the thick atmosphere of Venus, but its spectral parameters are still very limited due to the difficulty of detecting it in the laboratory. It is the highest overtone (ν{sub 1} + 5ν{sub 3}) of CO{sub 2} given in widely used spectroscopy databases such as HITRAN and GEISA. In the present work, the band is studied using a cavity ring-down spectrometer with ultra-high sensitivity as well as high precision. The positions of 55 lines in the band were determined with an absolute accuracy of 3 × 10{sup –5} cm{sup –1}, two orders of magnitude better than previous studies. The line intensities, self-induced pressure broadening coefficients, and the shift coefficients were also derived from the recorded spectra. The obtained spectral parameters can be applied to model the spectra of the CO{sub 2}-rich atmospheres of planets like Venus and Mars.
Authors:
; ; ; ; ; ; ;  [1]
  1. Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei 230026 (China)
Publication Date:
OSTI Identifier:
22270958
Resource Type:
Journal Article
Resource Relation:
Journal Name: Astrophysical Journal; Journal Volume: 775; Journal Issue: 1; Other Information: Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 79 ASTROPHYSICS, COSMOLOGY AND ASTRONOMY; ABSORPTION SPECTRA; ABSORPTION SPECTROSCOPY; ASTRONOMY; ASTROPHYSICS; CARBON DIOXIDE; EARTH ATMOSPHERE; EMISSION SPECTRA; EMISSION SPECTROSCOPY; MARS PLANET; PLANETARY ATMOSPHERES; SENSITIVITY; VENUS PLANET