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Title: CdO-CdS nano-composites as improved photo-catalysts for the generation of hydrogen from water

Journal Article · · AIP Conference Proceedings
DOI:https://doi.org/10.1063/1.4872572· OSTI ID:22269440
;  [1]; ;  [2]
  1. Department of Physics, University of Pune, Pune-411 007 (India)
  2. Chemistry Division, Bhabha Atomic Research Center, Trombay, Mumbai- 400 085 (India)

CdO-CdS nanocomposites were prepared by polyol method followed by heating at 300°C. XRD study confirmed the atomic scale mixing of CdO and CdS nanoparticles, leading to the formation of CdSO{sub 3} phase at the interfacial region between CdO and CdS. The enhancement in photo-catalytic activity for hydrogen generation from water is observed in case of CdO-CdS nanocomposites compared to individual CdS and CdO nanoparticles. Based on XRD, steady state and time resolved luminescence studies and surface area measurements, it is determined that, the fine mixing of CdS and CdO, higher surface area of the composite sample and increase in lifetime of the charge carriers are responsible for the observed increase in hydrogen yield from water when composite sample was used as the photo-catalyst compared to individual components.

OSTI ID:
22269440
Journal Information:
AIP Conference Proceedings, Vol. 1591, Issue 1; Conference: 58. DAE solid state physics symposium 2013, Patiala, Punjab (India), 17-21 Dec 2013; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0094-243X
Country of Publication:
United States
Language:
English