Structure-property-relationship of p-toluidinium tetrachloromercurate(II)

Dinesh,; Kumar, Mukesh; Dalela, S.

doi:10.1063/1.4872919

Title: Structure-property-relationship of p-toluidinium tetrachloromercurate(II)

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Abstract

The single crystals of p-toluidinium tetrachloromercurate(II) hybrid materials have been grown with perfect crystal of size 0.35 × 0.30 × 0.27 mm. The hybrid material is exposed to X-rays for 3D intensity data which is used to refine the crystal structure upto reliability-factor of 0.034. The phenyl ring has planar conformation with skeletal torsion angle of 0.003(6)° and the aromatic ring (C1-C6) forms an angle of 78.7(1)° to the plane of inorganic layer. The N-H...Cl hydrogen bonded tetramer pattern is observed in p-toluidinium tetrachloromercurate(II) and the two tetramer layers are separated by a distance of 3.925(6)Å and the minimum distance between two mercury atoms is 4.112(1)Å which is quite larger for any metallophilic interaction. The inorganic layers form zig-zag ribbons which are separated by a distance of 12.987(5)Å.

Authors:

Dinesh, ^[1]; Kumar, Mukesh ^[2]; Dalela, S. ^[3]

Department of Physics, Govt. G.M. Science College, Jammu -180006 (India)
School of Physical Sciences, Banasthali University, Banasthali, Rajasthan -304022 (India)
Department of Pure and Applied Physics, University of Kota, Kota, Rajasthan -324005 (India)

Publication Date:: Thu Apr 24 00:00:00 EDT 2014

OSTI Identifier:: 22269283

Resource Type:: Journal Article

Journal Name:: AIP Conference Proceedings

Additional Journal Information:: Journal Volume: 1591; Journal Issue: 1; Conference: 58. DAE solid state physics symposium 2013, Patiala, Punjab (India), 17-21 Dec 2013; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0094-243X

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CRYSTAL STRUCTURE; INTERACTIONS; LAYERS; MERCURY; MONOCRYSTALS; X RADIATION

Citation Formats


                    Dinesh,, Kumar, Mukesh, and Dalela, S. Structure-property-relationship of p-toluidinium tetrachloromercurate(II).  United States: N. p., 2014. 
        Web.  doi:10.1063/1.4872919.

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                    Dinesh,, Kumar, Mukesh, & Dalela, S. Structure-property-relationship of p-toluidinium tetrachloromercurate(II).  United States.  https://doi.org/10.1063/1.4872919

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                    Dinesh,, Kumar, Mukesh, and Dalela, S. 2014.  
        "Structure-property-relationship of p-toluidinium tetrachloromercurate(II)".  United States.  https://doi.org/10.1063/1.4872919.

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@article{osti_22269283,

  title        = {Structure-property-relationship of p-toluidinium tetrachloromercurate(II)},

  author       = {Dinesh, and Kumar, Mukesh and Dalela, S.},

  abstractNote = {The single crystals of p-toluidinium tetrachloromercurate(II) hybrid materials have been grown with perfect crystal of size 0.35 × 0.30 × 0.27 mm. The hybrid material is exposed to X-rays for 3D intensity data which is used to refine the crystal structure upto reliability-factor of 0.034. The phenyl ring has planar conformation with skeletal torsion angle of 0.003(6)° and the aromatic ring (C1-C6) forms an angle of 78.7(1)° to the plane of inorganic layer. The N-H...Cl hydrogen bonded tetramer pattern is observed in p-toluidinium tetrachloromercurate(II) and the two tetramer layers are separated by a distance of 3.925(6)Å and the minimum distance between two mercury atoms is 4.112(1)Å which is quite larger for any metallophilic interaction. The inorganic layers form zig-zag ribbons which are separated by a distance of 12.987(5)Å.},

  doi          = {10.1063/1.4872919},

  url          = {https://www.osti.gov/biblio/22269283},
  journal      = {AIP Conference Proceedings},

  issn         = {0094-243X},

  number       = 1,

  volume       = 1591,

  place        = {United States},

  year         = {Thu Apr 24 00:00:00 EDT 2014},

  month        = {Thu Apr 24 00:00:00 EDT 2014}

}

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