Synthesis and characterization of two dimensional metal organic framework of cerium with tetraaza macrocyclic

Bt Safiin, Nurul Atikah; Yarmo, Ambar; Yamin, Bohari M.

doi:10.1063/1.4858762

Title: Synthesis and characterization of two dimensional metal organic framework of cerium with tetraaza macrocyclic

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Abstract

A two dimensional metal organic framework containing cerium sufate layers and ethylenediaminium between layers was obtained by refluxing the mixture of cerium sulphate and 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-7, 14-diene bromide. The complex was characterized by infrared spectroscopy and microelemental analysis. X-ray study showed that the complex adopts eleven coordination environments about the central atom. Thermogravimetric study showed the removal of water molecules at about 70°C followed by a gradual mass loss until the whole structure collapsed at about 400°C.

Authors:

Bt Safiin, Nurul Atikah; Yarmo, Ambar; Yamin, Bohari M. ^[1]

School of Chemical Science and Food Technology. Faculty Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor Darul Ehsan (Malaysia)

Publication Date:: Wed Nov 27 00:00:00 EST 2013

OSTI Identifier:: 22262654

Resource Type:: Journal Article

Journal Name:: AIP Conference Proceedings

Additional Journal Information:: Journal Volume: 1571; Journal Issue: 1; Conference: 2013 UKM FST postgraduate colloquium, Selangor (Malaysia), 3-4 Jul 2013; Other Information: (c) 2013 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); Journal ID: ISSN 0094-243X

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ABSORPTION SPECTROSCOPY; BROMIDES; CERIUM; INFRARED SPECTRA; MIXTURES; ORGANOMETALLIC COMPOUNDS; SULFATES; SYNTHESIS; THERMAL GRAVIMETRIC ANALYSIS; X RADIATION

Citation Formats


                    Bt Safiin, Nurul Atikah, Yarmo, Ambar, and Yamin, Bohari M. Synthesis and characterization of two dimensional metal organic framework of cerium with tetraaza macrocyclic.  United States: N. p., 2013. 
        Web.  doi:10.1063/1.4858762.

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                    Bt Safiin, Nurul Atikah, Yarmo, Ambar, & Yamin, Bohari M. Synthesis and characterization of two dimensional metal organic framework of cerium with tetraaza macrocyclic.  United States.  https://doi.org/10.1063/1.4858762

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                    Bt Safiin, Nurul Atikah, Yarmo, Ambar, and Yamin, Bohari M. 2013.  
        "Synthesis and characterization of two dimensional metal organic framework of cerium with tetraaza macrocyclic".  United States.  https://doi.org/10.1063/1.4858762.

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@article{osti_22262654,

  title        = {Synthesis and characterization of two dimensional metal organic framework of cerium with tetraaza macrocyclic},

  author       = {Bt Safiin, Nurul Atikah and Yarmo, Ambar and Yamin, Bohari M.},

  abstractNote = {A two dimensional metal organic framework containing cerium sufate layers and ethylenediaminium between layers was obtained by refluxing the mixture of cerium sulphate and 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-7, 14-diene bromide. The complex was characterized by infrared spectroscopy and microelemental analysis. X-ray study showed that the complex adopts eleven coordination environments about the central atom. Thermogravimetric study showed the removal of water molecules at about 70°C followed by a gradual mass loss until the whole structure collapsed at about 400°C.},

  doi          = {10.1063/1.4858762},

  url          = {https://www.osti.gov/biblio/22262654},
  journal      = {AIP Conference Proceedings},

  issn         = {0094-243X},

  number       = 1,

  volume       = 1571,

  place        = {United States},

  year         = {Wed Nov 27 00:00:00 EST 2013},

  month        = {Wed Nov 27 00:00:00 EST 2013}

}

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https://doi.org/10.1063/1.4858762

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