skip to main content

Title: Complexation of di-amides of dipicolinic acid with neodymium

Di-amides have undergone significant studies as possible ligands for use in the partitioning of trivalent minor actinides and lanthanides. The binding affinities of three isomeric ligands with neodymium in acetonitrile solution have been investigated. The stability constants of the metal-ligand complexes formed between different isomers of N,N'-diethyl-N,N'- ditolyl-di-picolinamide (EtTDPA) and trivalent neodymium in acetonitrile have been determined by spectrophotometric and calorimetric methods. Each isomer of EtTDPA has been found to be capable of forming three complexes with trivalent neodymium, Nd(EtTDPA), Nd(EtTDPA){sub 2}, and Nd(EtTDPA){sub 3}. Values from spectrophotometric and calorimetric titrations are within reasonable agreement with each other. The order of stability constants for each metal:ligand complex decreases in the order Et(m)TDPA > Et(p)TDPA > Et(o)TDPA. The obtained values are comparable to other di-amidic ligands obtained under similar system conditions and mirror previously obtained solvent extraction data for EtTDPA at low ionic strengths. (authors.
Authors:
;  [1]
  1. Department of Chemistry, Oregon State University: 100 Radiation Center, Corvallis, OR 97331 (United States)
Publication Date:
OSTI Identifier:
22257876
Resource Type:
Conference
Resource Relation:
Conference: GLOBAL 2013: International Nuclear Fuel Cycle Conference - Nuclear Energy at a Crossroads, Salt Lake City, UT (United States), 29 Sep - 3 Oct 2013; Other Information: Country of input: France; 19 refs.; Related Information: In: Proceedings of GLOBAL 2013: International Nuclear Fuel Cycle Conference - Nuclear Energy at a Crossroads| 1633 p.
Publisher:
American Nuclear Society - ANS; La Grange Park (United States)
Research Org:
American Nuclear Society, 555 North Kensington Avenue, La Grange Park, IL 60526 (United States)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS; 12 MANAGEMENT OF RADIOACTIVE WASTES, AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; ACETONITRILE; ACTINIDES; AMIDES; CALORIMETRY; COMPARATIVE EVALUATIONS; COMPLEXES; ISOMERS; LIGANDS; NEODYMIUM; SOLVENT EXTRACTION; SPECTROPHOTOMETRY; STABILITY; TITRATION