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Title: Mass-dependent and -independent fractionation of isotopes in Ni and Pb chelate complex formation reactions

Mass independent fractionation (MIF) has been a very interesting topic in the field of inorganic isotope chemistry, in particular, geo- and cosmo- chemistry. In the present work, we studied the isotope fractionation of Ni(II) and Pb(II) ions in complex formation with chelating reagent EDTA. To obtain clear results on the mass dependence of the isotope fractionation, we have conducted long-distance ion exchange chromatography of Ni(II) and Pb(II), using chelate complex reagent EDTA. The results apparently show that the isotope fractionation in Ni complex formation system is governed by the mass dependent rule. On the other hand the isotope fractionation in the Pb complex system is governed by the mass independent rule or the nuclear volume effect.
Authors:
; ; ; ;  [1]
  1. Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology, O-okayama Meguroku, Tokyo, 152-8550 (Japan)
Publication Date:
OSTI Identifier:
22257193
Resource Type:
Journal Article
Resource Relation:
Journal Name: AIP Conference Proceedings; Journal Volume: 1565; Journal Issue: 1; Conference: PIM 2013: International conference on processes in isotopes and molecules, Cluj Napoca (Romania), 25-27 Sep 2013; Other Information: (c) 2013 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; CHELATES; EDTA; FRACTIONATION; ION EXCHANGE CHROMATOGRAPHY; LEAD COMPLEXES; NICKEL COMPLEXES; REAGENTS