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Title: Dielectric breakdown properties of hot SF{sub 6}-CO{sub 2} mixtures at temperatures of 300–3500 K and pressures of 0.01–1.0 MPa

Recently, much attention has been paid to SF{sub 6}-CO{sub 2} mixtures as one of substitutes for pure SF{sub 6} gas. In this paper, the dielectric breakdown properties of hot SF{sub 6}-CO{sub 2} mixtures are investigated at temperatures of 300–3500 K and pressures of 0.01–1.0 MPa. Under the assumptions of local thermodynamic equilibrium and local chemical equilibrium, the equilibrium compositions of hot SF{sub 6}-CO{sub 2} mixtures with different CO{sub 2} proportions are obtained based on Gibbs free energy minimization. The cross sections for interactions between electrons and neutral species are presented. Some unknown ionization cross sections are determined theoretically using Deutsch–Märk (DM) formalism based on quantum chemistry. Two-term Boltzmann equation is adopted to calculate the electron energy distribution function, reduced ionization coefficient, reduced attachment coefficient, and reduced effective ionization coefficient. Then the reduced critical electric field strength of mixtures, corresponding to dielectric breakdown performances, is determined when the generation and loss of electrons are balanced. Finally, the influences of temperature, pressure, and CO{sub 2} proportion on the reduced critical electric field strength are studied. It is found that a large percentage of CO{sub 2} can obviously reduce concentrations of high-energy electrons. At temperatures above 1750 K, an addition of CO{sub 2} to SF{sub 6}more » gas can enhance dielectric breakdown performances. However, at low temperatures, too much CO{sub 2} added into mixtures can reduce dielectric breakdown abilities. In addition, increasing gas pressure can improve dielectric breakdown performances. But the influence will be no more significant if pressure is over 0.8 MPa.« less
Authors:
; ; ; ; ;  [1]
  1. State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University, Xi'an 710049 (China)
Publication Date:
OSTI Identifier:
22252853
Resource Type:
Journal Article
Resource Relation:
Journal Name: Physics of Plasmas; Journal Volume: 21; Journal Issue: 5; Other Information: (c) 2014 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
70 PLASMA PHYSICS AND FUSION TECHNOLOGY; BOLTZMANN EQUATION; BREAKDOWN; CARBON DIOXIDE; CONCENTRATION RATIO; DIELECTRIC MATERIALS; ELECTRIC FIELDS; ELECTRONS; ENERGY SPECTRA; FREE ENTHALPY; IONIZATION; LTE; MINIMIZATION; MIXTURES; PERFORMANCE; SULFUR FLUORIDES