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Title: Polarization of positronium in amorphous polar polymers: A case study

Journal Article · · Journal of Chemical Physics
DOI:https://doi.org/10.1063/1.4832321· OSTI ID:22251371
 [1]
  1. Department of Aerospace Science and Technology, Politecnico di Milano, via La Masa, 34, Milano 20156 (Italy)

The features of positronium in an amorphous copolymer (polyvinyl acetate-crotonic acid) in a range of temperatures including the glass transition were investigated by means of positron annihilation lifetime spectroscopy. In particular, para-positronium lifetime was found to be longer than in a vacuum and to decrease with the temperature. This was attributed to the electron density at the positron (contact density), which is lower than in vacuo due to the presence of polar groups in the copolymer. A three quantum yield experiment confirmed the lifetime results.

OSTI ID:
22251371
Journal Information:
Journal of Chemical Physics, Vol. 139, Issue 20; Other Information: (c) 2013 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA); ISSN 0021-9606
Country of Publication:
United States
Language:
English

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