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Title: Low-energy inverse photoemission spectroscopy using a high-resolution grating spectrometer in the near ultraviolet range

An inverse photoemission spectroscopy (IPES) apparatus using a Czerny-Turner grating spectrometer is demonstrated. Previous IPES instruments based on grating spectrometers used a concave grating and operated in the vacuum ultraviolet range. The reflectance of such gratings is lower than 20% and the aberration cannot be finely corrected leading to an energy resolution of up to 0.1 eV. In the present study, employing the low energy IPES regime [H. Yoshida, Chem. Phys. Lett. 539–540, 180 (2012)], incident electrons with a kinetic energy below 5 eV are used, while photon emission in the range of between 250 and 370 nm is analyzed with a 10-cm Czerny-Turner grating spectrometer. The signal intensity is at least 30 times higher than the previous apparatus. The resolution of photon detection is set at 0.07 eV though the ultimate resolution is one order of magnitude higher. The experiment is performed both by sweeping the electron energy (isochromat mode) and by simultaneously analyzing the photon of whole wavelength range (tunable photon energy mode)
Authors:
 [1]
  1. Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011 (Japan)
Publication Date:
OSTI Identifier:
22220390
Resource Type:
Journal Article
Resource Relation:
Journal Name: Review of Scientific Instruments; Journal Volume: 84; Journal Issue: 10; Other Information: (c) 2013 AIP Publishing LLC; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND TECHNOLOGY; DETECTION; ENERGY RESOLUTION; EQUIPMENT; EV RANGE; GRATINGS; KINETIC ENERGY; PHOTOEMISSION; PHOTON EMISSION; PHOTONS; SIGNALS; SPECTROMETERS; SPECTROSCOPY; ULTRAVIOLET RADIATION; WAVELENGTHS