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Title: Crystal structure of bis(isothiocyanato)[2,6-diacetylpyridine bis(4-hydroxybenzoylhydrazone)]Fe(III) Chloride bis(dimethylformamide) solvate

The crystal structure of title compound (Fe[(C{sub 25}H{sub 21}N{sub 7}O{sub 4}S{sub 2})] {center_dot} 4(C{sub 3}NOH{sub 7}), where C{sub 3}NOH{sub 7} is dimethylformamide, DMF) was determined by the X-ray diffraction method. This compound crystallizes in the monoclinic C2/c space group, Z = 4. Unit cell parameters are: a = 13.6080(5), b = 17.6375(7), c = 19.5571(6) A, {beta} = 108.753(2) Degree-Sign . The N-H...O and O-H...O interactions stabilize the molecules in the lattice. The structure contains also the solvent dimethylformamide molecules, which are connected with intermoleculer hydrogen bond. The O atoms of DMF molecules take place as acceptor atoms.
Authors:
 [1] ;  [2] ;  [3] ;  [4]
  1. Aksaray University, Department of Physics, Arts and Sciences Faculty (Turkey)
  2. Gazi University, Department of Physics Education, Gazi Education Faculty (Turkey)
  3. Ondokuz Mayis University, Department of Physics, Arts and Sciences Faculty (Turkey)
  4. Mugla University, Department of Chemistry, Arts and Sciences Faculty (Turkey)
Publication Date:
OSTI Identifier:
22156468
Resource Type:
Journal Article
Resource Relation:
Journal Name: Crystallography Reports; Journal Volume: 58; Journal Issue: 1; Other Information: Copyright (c) 2013 Pleiades Publishing, Ltd.; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; CHLORIDES; INTERACTIONS; MONOCLINIC LATTICES; SOLVENTS; SPACE GROUPS; X-RAY DIFFRACTION