Synthesis and X-ray crystal structure determination of N-p-methylphenyl-4-benzoyl-3,4-diphenyl-2-azetidinone

Journal Article · Wed Dec 15 00:00:00 EST 2010 · Crystallography Reports

DOI:https://doi.org/10.1134/S1063774510070229· OSTI ID:22054040

Kabak, Mehmet ^[1]; Senoez, Huelya ^[2]; Elmali, Ayhan ^[1]; Adar, Vildan ^[2]; Svoboda, Ingrid ^[3]; Dusek, Michal; Fejfarova, Karla ^[4]

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1. University of Ankara, Department of Engineering Physics, Faculty of Engineering (Turkey)
2. Hacettepe University, Faculty of Sciences, Department of Chemistry (Turkey)
3. Darmstadt University of Technology, Institute of Material Science (Germany)
4. Institute of Physics (Czech Republic)

The title compound, C{sub 29}H{sub 23}NO{sub 2}, has been characterized by single-crystal X-ray diffraction at two different temperatures (303 K and 120 K) and wavelengths (MoK{sub {alpha}} and CuK{sub {alpha}}). The non-centrosymmetric hexagonal crystal structure contains four-membered planar {beta}-lactam ring with an unusually long C-C bond. The {beta}-lactam ring is almost planar.

• OSTI ID: 22054040
• Journal Information: Crystallography Reports, Vol. 55, Issue 7; Other Information: Copyright (c) 2010 Pleiades Publishing, Ltd.; Country of input: International Atomic Energy Agency (IAEA); ISSN 1063-7745
• Country of Publication: United States
• Language: English

Related Subjects

75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
CRYSTAL STRUCTURE
MONOCRYSTALS
ORGANIC NITROGEN COMPOUNDS
SYNTHESIS
TEMPERATURE RANGE 0065-0273 K
TEMPERATURE RANGE 0273-0400 K
X RADIATION
X-RAY DIFFRACTION