Facile synthesis of {alpha}-MnO{sub 2} one-dimensional (1D) nanostructure and energy storage ability studies
- Department of Chemistry, Tarbiat Moallem University, PO Box: 31979-37551, Tehran (Iran, Islamic Republic of)
- Department of Optic and Spectroscopy, Lasers and Optics Research School, NSTRI, PO Box: 11365-8486, Tehran (Iran, Islamic Republic of)
The dense manganese oxide nanorods with an extremely narrow distribution are synthesized at a low temperature using first cathodic electrodeposition subsequently heat treatment. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) images show that the nanorods have bar shapes, and their average diameter is less than 50 nm. The Fourier transform infrared (FT-IR) study, the selected area electron diffraction (SAED) pattern in TEM images and the X-ray diffraction (XRD) result show that the nanorods are {alpha}-MnO{sub 2} single crystal. The results of N{sub 2} adsorption-desorption analysis indicate that the BET surface area of the {alpha}-MnO{sub 2} nanorods is 93 m{sup 2} g{sup -1}. By recording the potential-time curve during the electrodeposition process, it is revealed that water reduction reaction has a major role in the electrogeneration of base at the cathode surface under the applied electrochemical conditions. Finally, based on the H{sub 2} bubbling on the cathode surface, the mechanism of the formation and the growth of {alpha}-MnO{sub 2} nanorods are proposed and discussed. For the electrochemical supercapacitor application, electrochemically prepared {alpha}-MnO{sub 2} is found to be stable for a large number of cycles with high specific capacitance, 338 F g{sup -1} at a scan rate of 10 mV s{sup -1}. Finally, the charge-discharge mechanism is discussed. - Graphical abstract: Highlights: Black-Right-Pointing-Pointer New nanostructures of MnO{sub 2} is synthesized by simple method of cathodicelectrodeposition. Black-Right-Pointing-Pointer The product has unique one-dimensional morphology with average diameter size of 50 nm. Black-Right-Pointing-Pointer The experiment conditions (temperature, current density) has not been reported. Black-Right-Pointing-Pointer The one-nanostructures obtained without using of hard template or surfactant.
- OSTI ID:
- 22012148
- Journal Information:
- Journal of Solid State Chemistry, Vol. . 190; Other Information: Copyright (c) 2012 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; Country of input: International Atomic Energy Agency (IAEA); ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
Similar Records
Synthesis and electrochemical properties of nanosized LiFeO{sub 2} particles with a layered rocksalt structure for lithium batteries
Hydrothermal synthesis and magnetic properties of {alpha}-MnO{sub 2} nanowires
Related Subjects
37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ADSORPTION
DESORPTION
ELECTRODEPOSITION
ELECTRON DIFFRACTION
FOURIER TRANSFORMATION
HEAT TREATMENTS
INFRARED SPECTRA
MANGANESE OXIDES
MONOCRYSTALS
NANOSTRUCTURES
ONE-DIMENSIONAL CALCULATIONS
SCANNING ELECTRON MICROSCOPY
SHAPE
SURFACE AREA
SURFACES
SURFACTANTS
SYNTHESIS
TRANSMISSION ELECTRON MICROSCOPY
X-RAY DIFFRACTION