Morphology-controlled synthesis and novel microwave electromagnetic properties of hollow urchin-like chain Fe-doped MnO{sub 2} under 10 T high magnetic field
- Department of Materials Processing Engineering, School of Materials Science and Engineering, Dalian University of Technology, Linggong Road 2, Ganjingzi District, Dalian, Liaoning Province 116085 (China)
Fe-doped MnO{sub 2} with a hollow sea urchin-like ball chain shape was first synthesized under a high magnetic field of 10 T. The formation mechanism was investigated and discussed in detail. The synthesized samples were characterized by XRD, SEM, TEM, EMPA, and vector network analysis. By doping MnO{sub 2} with Fe, the relative complex permittivity of MnO{sub 2} and its corresponding loss tangent clearly decreases, but its relative complex permeability and its corresponding loss tangent markedly increases. Moreover, the theoretically calculated values of reflection loss show that with increasing the Fe content, the as-prepared Fe-doped MnO{sub 2} exhibits good microwave absorption capability. -- Graphical Abstract: Fe-doped MnO{sub 2} with a hollow sea urchin-like ball chain shape was first synthesized in a high magnetic field of 10 T via a simple chemical process. Display Omitted Highlights: {yields} Fe-doped MnO{sub 2} with a hollow sea urchin-like ball chain shape was first synthesized. {yields} We investigated formation mechanism and electromagnetic properties of the Fe-doped MnO{sub 2}. {yields} By doping MnO{sub 2} with Fe, the electromagnetic properties are improved obviously.
- OSTI ID:
- 21494291
- Journal Information:
- Journal of Solid State Chemistry, Vol. 184, Issue 5; Other Information: DOI: 10.1016/j.jssc.2011.03.007; PII: S0022-4596(11)00104-6; Copyright (c) 2011 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ABSORPTION
DOPED MATERIALS
IRON COMPOUNDS
MAGNETIC FIELDS
MANGANESE OXIDES
MICROWAVE RADIATION
MORPHOLOGY
NETWORK ANALYSIS
PERMEABILITY
PERMITTIVITY
SCANNING ELECTRON MICROSCOPY
SYNTHESIS
TRANSMISSION ELECTRON MICROSCOPY
X-RAY DIFFRACTION
CHALCOGENIDES
COHERENT SCATTERING
DIELECTRIC PROPERTIES
DIFFRACTION
ELECTRICAL PROPERTIES
ELECTROMAGNETIC RADIATION
ELECTRON MICROSCOPY
MANGANESE COMPOUNDS
MATERIALS
MICROSCOPY
OXIDES
OXYGEN COMPOUNDS
PHYSICAL PROPERTIES
RADIATIONS
SCATTERING
SORPTION
TRANSITION ELEMENT COMPOUNDS