Two new hybrid compounds assembled from Keggin-type polyoxometalates and transition metal coordination complexes
- College of Chemistry, Jilin University, Changchun 130023 (China)
Two new hybrid compounds based on Keggin-type polyoxometalates: {l_brace}[PMo{sub 12}O{sub 40}][Ni(Phen){sub 2}(H{sub 2}O)]{sub 2{r_brace}}.K.2OH{sup -} (1) and [Cd{sub 2}(Phen){sub 4}Cl{sub 2}][HPW{sub 12}O{sub 40}].H{sub 2}O (2) (Phen=1,10-phenanthroline), have been prepared and characterized by IR, UV-vis, XPS, XRD and single crystal X-ray diffraction analyses. Compound 1 exhibits a 1-D chain structure constructed from Pseudo-Keggin polyoxometalate bi-supported transition metal coordination complexes linked by K{sup +} ions. Compound 2 contains Pseudo-Keggin polyoxoanions [HPW{sub 12}O{sub 40}]{sup 2-} and novel metal-chloride-ligand coordination complexes [Cd{sub 2}(Phen){sub 4}Cl{sub 2}]{sup 2+}. -- Graphical abstract: Two new hybrid compounds based on different Keggin-type polyoxometalates have been hydrothermally synthesized and characterized by IR, UV-Vis, XPS, XRD, elemental analysis and single crystal X-ray diffraction analysis. Display Omitted Research highlights: {yields} Two hybrids based on Pseudo-Keggin polyanions and metal coordination complexes. {yields} 1-D structure formed by polyanion bisupported metal coordination units linked by K{sup +}. {yields} A metal-chloride-ligand coordination complex [Cd{sub 2}(Phen){sub 4}Cl{sub 2}]{sup 2+}. {yields} A hybrid based on polyanions and metal-chloride-ligand coordination complexes.
- OSTI ID:
- 21494230
- Journal Information:
- Journal of Solid State Chemistry, Vol. 184, Issue 3; Other Information: DOI: 10.1016/j.jssc.2011.01.009; PII: S0022-4596(11)00010-7; Copyright (c) 2011 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CHLORIDES
HYDROTHERMAL SYNTHESIS
LIGANDS
MONOCRYSTALS
PHENANTHROLINES
TRANSITION ELEMENT COMPLEXES
X-RAY DIFFRACTION
X-RAY PHOTOELECTRON SPECTROSCOPY
AROMATICS
AZAARENES
CHLORINE COMPOUNDS
COHERENT SCATTERING
COMPLEXES
CRYSTALS
DIFFRACTION
ELECTRON SPECTROSCOPY
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PHOTOELECTRON SPECTROSCOPY
SCATTERING
SPECTROSCOPY
SYNTHESIS