Polyoxometalate-based eight-connected self-catenated network and fivefold interpenetrating framework

Journal Article · Fri Jan 15 00:00:00 EST 2010 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/j.jssc.2009.10.016· OSTI ID:21372472

Zhiming, Zhang; Jia, Liu; Yangguang, Li; Shuang, Yao ^[1]; Xinlong, Wang ^[1]

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1. Key Laboratory of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Ren Min Street No. 5268, Changchun, Jilin 130024 (China)

Two entangled compounds [(bpy){sub 6}Cu{sup I}{sub 6}Cl{sub 3}(Mo{sup V}W{sub 5}O{sub 19})] (1) and [(bpy){sub 7}Cu{sup I}{sub 7}Cl{sub 2}(BW{sub 12}O{sub 40})].H{sub 2}O (2) (bpy=4,4'-bipyridine), have been successfully synthesized under hydrothermal conditions and characterized by element analysis, IR spectroscopy, thermal gravimetric analysis, X-ray photoelectron spectroscopy, and single crystal X-ray diffraction analyses. Compound 1 represents the first eight-connected self-penetrating network constructed from cuprous chloride clusters [Cu{sub 6}Cl{sub 3}] and Lindquist-type polyoxoanions. Compound 2 exhibits an interesting fivefold interpenetrating network consisting of Keggin polyoxoanions and Cu{sup +}-metal-organic framework. Crystal data of the two compounds are following: 1, triclinic, P1-bar, a=11.502(2) A, b=13.069(3) A, c=13.296(3) A, alpha=90.55(3){sup o}, beta=113.74(3){sup o}, gamma=110.48(3){sup o}, Z=1; 2, triclinic, P1-bar, a=12.341(3) A, b=13.119(3) A, c=15.367(3) A, alpha=99.12(3){sup o}, beta=90.53(3){sup o}, gamma=104.49(3){sup o}, Z=1. - Graphical abstract: Compound 1 is the POM-based unprecedented eight-connected self-penetrating organic-inorganic hybrid network constructed from the cuprous chloride clusters [Cu{sub 6}Cl{sub 3}], Lindquist-type polyoxoanions [Mo{sup V}W{sub 5}O{sub 19}], and the 4,4'-bipyridine ligands.

• OSTI ID: 21372472
• Journal Information: Journal of Solid State Chemistry, Vol. 183, Issue 1; Other Information: DOI: 10.1016/j.jssc.2009.10.016; PII: S0022-4596(09)00500-3; Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; ISSN 0022-4596
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BIPYRIDINES
BORON COMPOUNDS
CHLORIDES
COPPER COMPOUNDS
COPPER IONS
INFRARED SPECTRA
MOLECULAR CLUSTERS
MOLYBDENUM COMPOUNDS
MONOCRYSTALS
ORGANOMETALLIC COMPOUNDS
THERMAL GRAVIMETRIC ANALYSIS
TUNGSTATES
X-RAY DIFFRACTION
X-RAY PHOTOELECTRON SPECTROSCOPY
AZINES
CHARGED PARTICLES
CHEMICAL ANALYSIS
CHLORINE COMPOUNDS
COHERENT SCATTERING
CRYSTALS
DIFFRACTION
ELECTRON SPECTROSCOPY
GRAVIMETRIC ANALYSIS
HALIDES
HALOGEN COMPOUNDS
HETEROCYCLIC COMPOUNDS
IONS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
OXYGEN COMPOUNDS
PHOTOELECTRON SPECTROSCOPY
PYRIDINES
QUANTITATIVE CHEMICAL ANALYSIS
REFRACTORY METAL COMPOUNDS
SCATTERING
SPECTRA
SPECTROSCOPY
THERMAL ANALYSIS
TRANSITION ELEMENT COMPOUNDS
TUNGSTEN COMPOUNDS