Three-dimensional (3-D) metal-organic frameworks with 3-pyridin-4-yl-benzoate defining new (3,6)-connected net topologies
- College of Chemistry and Life Science, Tianjin Key Laboratory of Structure and Performance for Functional Molecule, Tianjin Normal University, Tianjin 300387 (China)
- State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071 (China)
Reactions of different metal salts with 3-pyridin-4-yl-benzoic acid (3,4-Hpybz) under ambient condition afford a series of 3-D metal-organic frameworks with two new types of (3,6)-connected net topologies. In the isomorphic complexes [M{sub 2}(mu-H{sub 2}O)(3,4-pybz){sub 4}]{sub n} (M{sup II}=Mn{sup II} for 1, Zn{sup II} for 2, or Cd{sup II} for 3), the octahedral metal nodes are extended by the 3-connected pybz tectons to constitute 3-D arrays with the Schlaefli symbol of (3.4.5)(3{sup 2}.4{sup 4}.5{sup 5}.6{sup 2}.7{sup 2}), whereas [Pb(3,4-pybz){sub 2}]{sub n} (4) shows a completely different 3-D (4{sup 2}.6){sub 2}(4{sup 4}.6{sup 2}.8{sup 9}) framework, which represents a subnet of the (4,8)-connected fluorite lattice. - Graphical abstract: This work presents a series of 3-D metal-organic frameworks with 3-pyridin-4-yl-benzoate, which display new (3,6)-connected net topologies of (3.4.5)(3{sup 2}.4{sup 4}.5{sup 5}.6{sup 2}.7{sup 2}) for Mn{sup II}/Zn{sup II}/Cd{sup II} and (4{sup 2}.6){sub 2}(4{sup 4}.6{sup 2}.8{sup 9}) for Pb{sup II} species.
- OSTI ID:
- 21372410
- Journal Information:
- Journal of Solid State Chemistry, Vol. 182, Issue 11; Other Information: DOI: 10.1016/j.jssc.2009.09.004; PII: S0022-4596(09)00424-1; Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
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Related Subjects
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
BENZOIC ACID
CADMIUM COMPLEXES
FLUORESCENCE
MANGANESE COMPLEXES
ORGANOMETALLIC COMPOUNDS
STABILITY
TOPOLOGY
ZINC COMPLEXES
CARBOXYLIC ACIDS
COMPLEXES
EMISSION
LUMINESCENCE
MATHEMATICS
MONOCARBOXYLIC ACIDS
ORGANIC ACIDS
ORGANIC COMPOUNDS
PHOTON EMISSION
TRANSITION ELEMENT COMPLEXES