The tunable coordination architectures of a flexible multicarboxylate N-(4-carboxyphenyl)iminodiacetic acid via different metal ions, pH values and auxiliary ligand

Journal Article · Wed Jul 15 00:00:00 EDT 2009 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/j.jssc.2009.05.007· OSTI ID:21370499

Xiaochuan, Chai ^[1]; Shuai, Zhang; Yanning, Cao; Yiping, Chen ^[1]

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1. Department of Chemistry, Fuzhou University, Fuzhou, Fujian 350108 (China)

{l_brace}[Pb{sub 3}(CPIDA){sub 2}(H{sub 2}O){sub 3}].H{sub 2}O{r_brace}{sub n}1, {l_brace}[Cd{sub 3}(CPIDA){sub 2}(H{sub 2}O){sub 4}].5H{sub 2}O{r_brace}{sub n}2, [Cd(HCPIDA)(bpy)(H{sub 2}O)]{sub n}3 (bpy=4,4'-bipyridine) and {l_brace}[Co{sub 3}(CPIDA){sub 2}(bpy){sub 3}(H{sub 2}O){sub 4}].2H{sub 2}O{r_brace}{sub n}4 were synthesized with N-(4-carboxyphenyl) iminodiacetic acid (H{sub 3}CPIDA). In 1, the CPIDA{sup 3-} ligands adopt chelating and bridging modes with Pb(II) to possess a 3D porous framework. In 2D-layer 2, the CPIDA{sup 3-} ligands display a simple bridging mode with Cd(II). The 2D layers have parallelogram-shaped channels along a axis. With bpy ligands, the HCPIDA{sup 2-} ligands in 3 show more abundant modes, but 3 still displays a 2D sheet on bc plane for the unidentate bpy molecules. However, in 3D-framework 4, the bpy ligands adopt bridging bidentate at a higher pH value and the CPIDA{sup 3-} ligands show bis-bidentate modes with Co(II). Additionally, 2D correlation analysis of FTIR was introduced to ascertain the characteristic adsorptions location of the carboxylate groups with different coordination modes in 4 with thermal and magnetic perturbation. Compounds 1, 2 and 4 exhibit the fluorescent emissions at room temperature. - Graphical abstract: A series of coordination polymers were synthesized with H{sub 3}CPIDA and transition metal ions at lower pH values. The figure displays a 3D porous framework with three parallel channels in compound 1.

• OSTI ID: 21370499
• Journal Information: Journal of Solid State Chemistry, Vol. 182, Issue 7; Other Information: DOI: 10.1016/j.jssc.2009.05.007; PII: S0022-4596(09)00199-6; Copyright (c) 2009 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved.; ISSN 0022-4596
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
ADSORPTION
AMINO ACIDS
BIPYRIDINES
CADMIUM COMPLEXES
CHELATING AGENTS
COBALT COMPLEXES
FLUORESCENCE
INFRARED SPECTRA
LEAD COMPLEXES
LIGANDS
PH VALUE
POLYMERS
POROUS MATERIALS
TEMPERATURE RANGE 0273-0400 K
AZINES
CARBOXYLIC ACIDS
COMPLEXES
EMISSION
HETEROCYCLIC COMPOUNDS
LUMINESCENCE
MATERIALS
ORGANIC ACIDS
ORGANIC COMPOUNDS
ORGANIC NITROGEN COMPOUNDS
PHOTON EMISSION
PYRIDINES
SORPTION
SPECTRA
TEMPERATURE RANGE
TRANSITION ELEMENT COMPLEXES