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Title: Increased nanopore filling: Effect on monolithic all-solid-state dye-sensitized solar cells

Journal Article · · Applied Physics Letters
DOI:https://doi.org/10.1063/1.2743381· OSTI ID:20971938
; ; ;  [1]
  1. Department of Materials Engineering, Monash University, Clayton, Victoria 3800 (Australia)

A vacuum pore-filling method is described to fabricate solid-state dye-sensitized solar cells (DSSCs) based on nanocomposite polymer electrolytes. Scanning electron microscopy and energy dispersive x-ray spectrometry analyses suggest that incomplete pore filling of the nanostructured TiO{sub 2} electrodes is a major efficiency-limiting factor in the fabrication process of solid-state DSSC. Application of the vacuum method resulted in DSSC with much improved energy conversion efficiencies when compared to devices made via conventional drop-casting technique. The energy conversion efficiency gain increased steadily with increasing TiO{sub 2} film thicknesses. It is expected that the vacuum pore-filling technique will be applicable to a wide range of hole-transport materials.

OSTI ID:
20971938
Journal Information:
Applied Physics Letters, Vol. 90, Issue 21; Other Information: DOI: 10.1063/1.2743381; (c) 2007 American Institute of Physics; Country of input: International Atomic Energy Agency (IAEA); ISSN 0003-6951
Country of Publication:
United States
Language:
English