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Title: Hydrothermal synthesis and structure of a novel 3D framework based on {xi}-octamolybdate chains: [Cu{sub 2}(quinoxaline){sub 2}Mo{sub 4}O{sub 13}]{sub n}

An unprecedented three-dimensional (3D) polymer [Cu{sub 2}(quinoxaline){sub 2}Mo{sub 4}O{sub 13}]{sub n}, formed from {xi}-octamolybdate chains as building units and pairs of 1D [Cu(quinoxaline)]{sub n}{sup n+} polymeric chains as linkers, provides the first example of an extended higher dimensional structure based on [Mo{sub 8}O{sub 26}]{sub n}{sup 4n-} octamolybdate chain. The basic building block of the octamolybdate chain included in the title compound is first reported to be constructed from {xi}-isomer of octamolybdate unit.
Authors:
 [1] ;  [2] ;  [1] ;  [1] ;  [1] ;  [3]
  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Yangqiao West Road 155, Fuzhou, Fujian 350002 (China)
  2. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, Yangqiao West Road 155, Fuzhou, Fujian 350002 (China). E-mail: czlu@ma.fiirsm.ac.cn
  3. School of Pharmacy, Fujian Medical University, Fuzhou, Fujian 350004 (China). E-mail: xhlin174@sina.com
Publication Date:
OSTI Identifier:
20905406
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Solid State Chemistry; Journal Volume: 179; Journal Issue: 8; Other Information: DOI: 10.1016/j.jssc.2006.04.054; PII: S0022-4596(06)00264-7; Copyright (c) 2006 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; COPPER COMPOUNDS; CRYSTAL STRUCTURE; HYDROTHERMAL SYNTHESIS; MOLYBDATES; MOLYBDENUM OXIDES; POLYMERS