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Title: Improved volume-averaged model for steady and pulsed-power electronegative discharges

Journal Article · · Journal of Vacuum Science and Technology. A, International Journal Devoted to Vacuum, Surfaces, and Films
DOI:https://doi.org/10.1116/1.2345645· OSTI ID:20853792
; ; ;  [1]
  1. Department of Electrical Engineering and Computer Sciences, University of California, Berkeley, California 94720-1770 (United States)

An improved volume-averaged global model is developed for a cylindrical (radius R, length L) electronegative (EN) plasma that is applicable over a wide range of electron densities, electronegativities, and pressures. It is applied to steady and pulsed-power oxygen discharges. The model incorporates effective volume and surface loss factors for positive ions, negative ions, and electrons combining three electronegative discharge regimes: a two-region regime with a parabolic EN core surrounded by an electropositive edge, a one-region parabolic EN plasma, and a one-region flat-topped EN plasma, spanning the plasma parameters and gas pressures of interest for low pressure processing (below a few hundred millitorr). Pressure-dependent effective volume and surface loss factors are also used for the neutral species. A set of reaction rate coefficients, updated from previous model calculations, is developed for oxygen for the species O{sub 2}, O{sub 2}({sup 1}{delta}{sub g}), O, O{sub 2}{sup +}, O{sup +}, and O{sup -}, based on the latest published cross-section sets and measurements. The model solutions yield all of the quantities above together with such important processing quantities such as the neutral/ion flux ratio {gamma}{sub O}/{gamma}{sub i}, with the discharge aspect ratio 2R/L and pulsed-power period and duty ratio (pulse on-time/pulse period) as parameters. The steady discharge results are compared to an experiment, giving good agreement. For steady discharges, increasing 2R/L from 1 to 6 leads to a factor of 0.45 reduction in {gamma}{sub O}/{gamma}{sub i}. For pulsed discharges with a fixed duty ratio, {gamma}{sub O}/{gamma}{sub i} is found to have a minimum with respect to pulse period. A 25% duty ratio pulse reduces {gamma}{sub O}/{gamma}{sub i} by a factor of 0.75 compared to the steady-state case.

OSTI ID:
20853792
Journal Information:
Journal of Vacuum Science and Technology. A, International Journal Devoted to Vacuum, Surfaces, and Films, Vol. 24, Issue 6; Other Information: DOI: 10.1116/1.2345645; (c) 2006 American Vacuum Society; Country of input: International Atomic Energy Agency (IAEA); ISSN 1553-1813
Country of Publication:
United States
Language:
English

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