Preparation of submicrometer-sized copper and silver crystallites by a facile solvothermal complexation-reduction route
Journal Article
·
· Journal of Solid State Chemistry
- College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou City 225002 (China)
Pure submicrometer-sized copper and silver crystallites have been directly synthesized via solvothermal treatment of CuCl{sub 2}.2H{sub 2}O or AgNO{sub 3} in ethylenediamine (EDA) at 80-180 deg. C for 15-20h, and characterized by means of X-ray powder diffraction, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and transmission electron microscopy. It was suggested that the formation of copper and silver crystallites in this solvothermal system be through a typical complexation-reduction process, in which EDA serves not only as a reducing reagent, but also as a complexing solvent.
- OSTI ID:
- 20725941
- Journal Information:
- Journal of Solid State Chemistry, Vol. 178, Issue 5; Other Information: DOI: 10.1016/j.jssc.2005.03.009; PII: S0022-4596(05)00089-7; Copyright (c) 2005 Elsevier Science B.V., Amsterdam, The Netherlands, All rights reserved; Country of input: International Atomic Energy Agency (IAEA); ISSN 0022-4596
- Country of Publication:
- United States
- Language:
- English
Similar Records
The new silver(I)thioantimonate(III) [C{sub 4}N{sub 2}H{sub 14}][Ag{sub 3}Sb{sub 3}S{sub 7}] and a new structural variant of the silver(I)thioantimonate(III) [C{sub 2}N{sub 2}H{sub 9}]{sub 2}[Ag{sub 5}Sb{sub 3}S{sub 8}] both synthesized under solvothermal conditions
Solvothermal hot injection synthesis of core-shell AgNi nanoparticles
0-D and 1-D inorganic-organic composite polyoxotungstates constructed from in-situ generated monocopper{sup II}-substituted Keggin polyoxoanions and copper{sup II}-organoamine complexes
Journal Article
·
Wed Nov 15 00:00:00 EST 2006
· Journal of Solid State Chemistry
·
OSTI ID:20725941
Solvothermal hot injection synthesis of core-shell AgNi nanoparticles
Journal Article
·
Sat Aug 11 00:00:00 EDT 2018
· Journal of Alloys and Compounds
·
OSTI ID:20725941
+2 more
0-D and 1-D inorganic-organic composite polyoxotungstates constructed from in-situ generated monocopper{sup II}-substituted Keggin polyoxoanions and copper{sup II}-organoamine complexes
Journal Article
·
Mon Sep 15 00:00:00 EDT 2008
· Journal of Solid State Chemistry
·
OSTI ID:20725941