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Title: Fano effect in the angle-integrated valence band photoemission of the noble metals Cu, Ag, and Au

Journal Article · · Physical Review. B, Condensed Matter and Materials Physics
;  [1]; ;  [2]; ;  [3]
  1. European Synchrotron Radiation Facility, Boite Postale 220, 38043 Grenoble Cedex (France)
  2. Department Chemie, Phys. Chemie, Universitaet Muenchen, Butenandtstr. 5-13, D-81377 Munich (Germany)
  3. INFM-Dip. di Fisica, Politecnico di Milano, p. Leonardo da Vinci 32, 20133 Milan (Italy)

Results of a combined experimental and theoretical investigation on the Fano-effect in the angle-integrated valence band photoemission of the noble metals are presented. In line with the fact that the Fano-effect is caused by the spin-orbit-coupling, the observed spin polarization of the photocurrent was found to be the more pronounced the higher the atomic number of the element investigated. The ratio of the normalized spin difference curves, however, agreed only for Cu and Ag with the ratio of the corresponding spin-orbit coupling strength parameters. The deviation from this expected behavior in the case of Au could be explained by the properties of individual d-p- and d-f-contributions to the total spin difference curves, that were found to be quite different for Au compared to Cu and Ag.

OSTI ID:
20664903
Journal Information:
Physical Review. B, Condensed Matter and Materials Physics, Vol. 70, Issue 13; Other Information: DOI: 10.1103/PhysRevB.70.134409; (c) 2004 The American Physical Society; Country of input: International Atomic Energy Agency (IAEA); ISSN 1098-0121
Country of Publication:
United States
Language:
English