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Title: Rotational symmetry control of electronic relaxation in ultracold gaseous molecules: Optical-optical double resonance probe of the forbidden T{sub 1}{yields}S{sub 0} intersystem crossing in jet-cooled thiophosgene, Cl{sub 2}CS

Abstract

Two-color optical-optical double resonance studies of the T{sub 1}{yields}S{sub 0} intersystem crossing in jet-cooled thiophosgene indicate that rotational symmetry strongly influences the efficiency of an intersystem crossing in symmetric molecules with low degrees of rotational excitation. (c) 2000 American Institute of Physics.

Authors:
 [1];  [2];  [3];  [3]
  1. Department of Chemistry, Brock University, St. Catharines, Ontario L2S 3A1 Canada (Canada)
  2. Department of Chemistry, University of Wisconsin-Parkside, Kenosha, Wisconsin 53141-2000 (United States)
  3. Department of Chemistry, The University of Akron, Akron, Ohio 44325-3601 (United States)
Publication Date:
OSTI Identifier:
20217436
Resource Type:
Journal Article
Journal Name:
Journal of Chemical Physics
Additional Journal Information:
Journal Volume: 113; Journal Issue: 10; Other Information: PBD: 8 Sep 2000; Journal ID: ISSN 0021-9606
Country of Publication:
United States
Language:
English
Subject:
74 ATOMIC AND MOLECULAR PHYSICS; DOUBLE RESONANCE METHODS; FORBIDDEN TRANSITIONS; PHOSGENE; ORGANIC SULFUR COMPOUNDS; RADIATIONLESS DECAY; ROTATIONAL STATES; EXCITATION; FLUORESCENCE; EXPERIMENTAL DATA

Citation Formats

Moule, David C, Judge, Richard H, Liu, Haisheng, and Lim, Edward C. Rotational symmetry control of electronic relaxation in ultracold gaseous molecules: Optical-optical double resonance probe of the forbidden T{sub 1}{yields}S{sub 0} intersystem crossing in jet-cooled thiophosgene, Cl{sub 2}CS. United States: N. p., 2000. Web. doi:10.1063/1.1290467.
Moule, David C, Judge, Richard H, Liu, Haisheng, & Lim, Edward C. Rotational symmetry control of electronic relaxation in ultracold gaseous molecules: Optical-optical double resonance probe of the forbidden T{sub 1}{yields}S{sub 0} intersystem crossing in jet-cooled thiophosgene, Cl{sub 2}CS. United States. https://doi.org/10.1063/1.1290467
Moule, David C, Judge, Richard H, Liu, Haisheng, and Lim, Edward C. 2000. "Rotational symmetry control of electronic relaxation in ultracold gaseous molecules: Optical-optical double resonance probe of the forbidden T{sub 1}{yields}S{sub 0} intersystem crossing in jet-cooled thiophosgene, Cl{sub 2}CS". United States. https://doi.org/10.1063/1.1290467.
@article{osti_20217436,
title = {Rotational symmetry control of electronic relaxation in ultracold gaseous molecules: Optical-optical double resonance probe of the forbidden T{sub 1}{yields}S{sub 0} intersystem crossing in jet-cooled thiophosgene, Cl{sub 2}CS},
author = {Moule, David C and Judge, Richard H and Liu, Haisheng and Lim, Edward C},
abstractNote = {Two-color optical-optical double resonance studies of the T{sub 1}{yields}S{sub 0} intersystem crossing in jet-cooled thiophosgene indicate that rotational symmetry strongly influences the efficiency of an intersystem crossing in symmetric molecules with low degrees of rotational excitation. (c) 2000 American Institute of Physics.},
doi = {10.1063/1.1290467},
url = {https://www.osti.gov/biblio/20217436}, journal = {Journal of Chemical Physics},
issn = {0021-9606},
number = 10,
volume = 113,
place = {United States},
year = {Fri Sep 08 00:00:00 EDT 2000},
month = {Fri Sep 08 00:00:00 EDT 2000}
}