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Title: Fac-Re(bpy)(CO){sub 3}(COOMe): A model metallocarboxylate complex of rhenium with a bipyridyl ligand

The title compound fac-(2,2{prime}-bipyridyl)(carbomethoxy)rhenium tricarbonyl, crystallizes in the monoclinic system, space group P2{sub 1}/c with the following crystal data: a = 8.37551(1), b = 6.6934(1), c = 26.2098(1) {angstrom}, V({angstrom}{sup 3}) = 1,535.93(3), Z = 4, and {beta} = 90.0971(2). The metal environment is slightly distorted octahedral with a chelating bipyridyl ligand and a facial arrangement of the carbon monoxide ligands.
Authors:
; ;
Publication Date:
OSTI Identifier:
20013134
Resource Type:
Journal Article
Resource Relation:
Journal Name: Journal of Chemical Crystallography; Journal Volume: 29; Journal Issue: 5; Other Information: PBD: May 1999
Research Org:
Univ. of Louisville, KY (US)
Sponsoring Org:
US Department of Energy; National Science Foundation
Country of Publication:
United States
Language:
English
Subject:
40 CHEMISTRY; CRYSTAL STRUCTURE; CARBOXYLIC ACID ESTERS; RHENIUM COMPLEXES; BIPYRIDINES; LIGANDS; LATTICE PARAMETERS