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Title: Homogeneous and supported catalysts for {alpha}-olefin hydrogenation based on complexes of platinum tetrachloride with aliphatic amines

Abstract

A new efficient catalyst for a-olefin hydrogenation, a reaction of importance to synthetic fuels preparation, that exhibits the catalytic activity without additional treatment with a reducing agent is obtained by the interaction of PtCl{sub 4} with tri-n-octylamine. Molecular hydrogen and ethanol are found to promote the catalytically active complex. On the basis of the IR spectroscopic investigation, a likely structure of the synthesized complex is proposed. A highly active heterogenized platinum-containing catalyst for the hydrogenation of terminal double bonds is prepared by supporting a homogeneous system on {gamma}-Al{sub 2}O{sub 3}.

Authors:
; ;  [1]
  1. Topchiev Institute of Petrochemical Synthesis, Moscow (Russian Federation)
Publication Date:
OSTI Identifier:
159599
Resource Type:
Journal Article
Journal Name:
Kinetics and Catalysis
Additional Journal Information:
Journal Volume: 36; Journal Issue: 4; Other Information: PBD: Jul-Aug 1995; TN: Translated from Kinetika i Kataliz; 36: No. 4, 546-549(1995)
Country of Publication:
United States
Language:
English
Subject:
10 SYNTHETIC FUELS; 40 CHEMISTRY; PLATINUM CHLORIDES; CATALYTIC EFFECTS; ALKENES; HYDROGENATION; SYNTHETIC FUELS; CHEMICAL PREPARATION; DOUBLE BONDS; ETHANOL; CATALYSTS; AMINES

Citation Formats

Kliger, E G, Shuikina, L P, and Frolov, V M. Homogeneous and supported catalysts for {alpha}-olefin hydrogenation based on complexes of platinum tetrachloride with aliphatic amines. United States: N. p., 1995. Web.
Kliger, E G, Shuikina, L P, & Frolov, V M. Homogeneous and supported catalysts for {alpha}-olefin hydrogenation based on complexes of platinum tetrachloride with aliphatic amines. United States.
Kliger, E G, Shuikina, L P, and Frolov, V M. 1995. "Homogeneous and supported catalysts for {alpha}-olefin hydrogenation based on complexes of platinum tetrachloride with aliphatic amines". United States.
@article{osti_159599,
title = {Homogeneous and supported catalysts for {alpha}-olefin hydrogenation based on complexes of platinum tetrachloride with aliphatic amines},
author = {Kliger, E G and Shuikina, L P and Frolov, V M},
abstractNote = {A new efficient catalyst for a-olefin hydrogenation, a reaction of importance to synthetic fuels preparation, that exhibits the catalytic activity without additional treatment with a reducing agent is obtained by the interaction of PtCl{sub 4} with tri-n-octylamine. Molecular hydrogen and ethanol are found to promote the catalytically active complex. On the basis of the IR spectroscopic investigation, a likely structure of the synthesized complex is proposed. A highly active heterogenized platinum-containing catalyst for the hydrogenation of terminal double bonds is prepared by supporting a homogeneous system on {gamma}-Al{sub 2}O{sub 3}.},
doi = {},
url = {https://www.osti.gov/biblio/159599}, journal = {Kinetics and Catalysis},
number = 4,
volume = 36,
place = {United States},
year = {Sat Jul 01 00:00:00 EDT 1995},
month = {Sat Jul 01 00:00:00 EDT 1995}
}