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Title: The role of the reaction CO + SH {yields} COS + H in hydrogen formation in the course of interaction between CO and H{sub 2}S

Journal Article · · Kinetics and Catalysis
OSTI ID:159595
;  [1]
  1. Sector of Radiation Studies, Baku (Russian Federation)

It is shown that the photochemically initiated chain reaction between CO and H{sub 2}S to form H{sub 2} Occurs via the hydrogen atom abstraction from SH{sup {sm_bullet}} radicals under the action of a CO molecule: CO + SH{sup {sm_bullet}} {r_arrow} COS + H. The value of the rate constant for this reaction is evaluated.

OSTI ID:
159595
Journal Information:
Kinetics and Catalysis, Vol. 36, Issue 4; Other Information: PBD: Jul-Aug 1995; TN: Translated from Kinetika i Kataliz; 36: No. 4, 498-500(1995)
Country of Publication:
United States
Language:
English