Selective Stationary Phase for Solid-Phase Microextraction Analysis of Sarin (GB)
A number of critical field applications require monitoring air samples for trace levels of chemical warfare agents. Solid-phase microextraction (SPME) is a convenient format to conduct these analyses. Measurements could be significantly improved if a SPME phase selective for nerve agents were substituted for nonselective polymers typically used (e.g.,polydimethylsiloxane). This paper evaluates a novel stationary phase, previously developed for methylphosphonate sensor applications, for use with SPME sampling. The phenol-based polymer, BSP3, was found to offer far higher selectivity toward sarin (GB) than polydimethylsiloxane due to a pronounced affinity toward the target analyte and a lower affinity toward hydrocarbons.
- Research Organization:
- Pacific Northwest National Lab., Richland, WA (US)
- Sponsoring Organization:
- US Department of Energy (US)
- DOE Contract Number:
- AC06-76RL01830
- OSTI ID:
- 15001304
- Report Number(s):
- PNNL-SA-35681; NN2001000; TRN: US200412%%470
- Journal Information:
- Journal of Chromatography A, Vol. 954, Issue 1-2; Other Information: PBD: 19 Apr 2002
- Country of Publication:
- United States
- Language:
- English
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