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Title: Solubility and Reaction Rates of Aluminum Solid Phases Under Hydrothermal Conditions

Experimental studies involving equilibrium solubility and dissolution/precipitation rates were initiated on boehmite (AIOOH) using a hydrogen-electrode concentration cell (HECC). This cell provides continuous, accurate in situ pH measurements of solid/solution mixtures to 295 C with provision for either removing solution samples for analysis of the metal content, or adding either of two titrants. This cell has been recently used to measure the solubility of minerals such as brucite; boehmite, zincite, arid magnetite. The ability to perturb pH, isothermally by addition of acidic or basic titrant opens the door for studies of the kinetics of dissolution/precipitation, even for relatively fast reactions. By monitoring the change in pH, with time, detailed kinetic information can be obtained without the need for sampling.
Authors:
; ;
Publication Date:
OSTI Identifier:
14625
Report Number(s):
ORNL/CP-103300
TRN: AH200129%%421
DOE Contract Number:
AC05-96OR22464
Resource Type:
Conference
Resource Relation:
Conference: Conference title not supplied, Conference location not supplied, Conference dates not supplied; Other Information: PBD: 14 Nov 1999
Research Org:
Oak Ridge National Lab., TN (US)
Sponsoring Org:
USDOE Office of Science (US)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; ALUMINIUM; DOORS; KINETICS; MAGNETITE; MIXTURES; MONITORING; REACTION KINETICS; SAMPLING; SOLUBILITY