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Title: High temperature hydrogen sulfide removal with tin oxide

Abstract

This Phase II SBIR contract is developing a sorbent and process which removes H{sub 2}S from hot gasified coal and generates sulfur during regeneration of the sorbent. The process can be used with any type of reactor (e.g., fixed or moving bed) and any gasifier (e.g., KRW or Texaco) and shows lower costs that competing H{sub 2}S removal processes. TDA Research`s (TDA) process uses a regenerable stannic oxide-based (SnO{sub 2}) sorbent as the first sorbent and zinc ferrite (or zinc titanate) as a second sorbent to remove H{sub 2}S to very low concentrations. The process converts the sulfides from both sorbents to elemental sulfur, a commercial product which is easy to store and transport. The object of this phase is to develop chemically active, high sulfur loadings, and durable stannic oxide sorbents and to demonstrate the process at the bench scale.

Authors:
; ; ; ;  [1]
  1. TDA Research, Inc., Wheat Ridge, CO (United States)
Publication Date:
Research Org.:
USDOE Morgantown Energy Technology Center (METC), WV (United States)
OSTI Identifier:
140668
Report Number(s):
DOE/METC-93/6131; CONF-9306148-
ON: DE93000289; TRN: 94:001376-0047
DOE Contract Number:  
FG03-90ER80998
Resource Type:
Conference
Resource Relation:
Conference: Coal-fired power systems `93: advances in IGCC and PFBC review meeting, Morgantown, WV (United States), 28-30 Jun 1993; Other Information: PBD: Jun 1993; Related Information: Is Part Of Proceedings of the coal-fired power systems 93: Advances in IGCC and PFBC review meeting; Bonk, D.L. [ed.]; PB: 786 p.
Country of Publication:
United States
Language:
English
Subject:
20 FOSSIL-FUELED POWER PLANTS; 01 COAL, LIGNITE, AND PEAT; COMBINED-CYCLE POWER PLANTS; HOT GAS CLEANUP; FUEL GAS; CLEANING; HYDROGEN SULFIDES; SEPARATION PROCESSES; TIN OXIDES; SORPTIVE PROPERTIES; ZINC COMPOUNDS; FERRITES; ADSORBENTS; COAL GASIFICATION

Citation Formats

Copeland, R J, Feinberg, D, Wickham, D, Windecker, B, and Yu, J. High temperature hydrogen sulfide removal with tin oxide. United States: N. p., 1993. Web.
Copeland, R J, Feinberg, D, Wickham, D, Windecker, B, & Yu, J. High temperature hydrogen sulfide removal with tin oxide. United States.
Copeland, R J, Feinberg, D, Wickham, D, Windecker, B, and Yu, J. 1993. "High temperature hydrogen sulfide removal with tin oxide". United States.
@article{osti_140668,
title = {High temperature hydrogen sulfide removal with tin oxide},
author = {Copeland, R J and Feinberg, D and Wickham, D and Windecker, B and Yu, J},
abstractNote = {This Phase II SBIR contract is developing a sorbent and process which removes H{sub 2}S from hot gasified coal and generates sulfur during regeneration of the sorbent. The process can be used with any type of reactor (e.g., fixed or moving bed) and any gasifier (e.g., KRW or Texaco) and shows lower costs that competing H{sub 2}S removal processes. TDA Research`s (TDA) process uses a regenerable stannic oxide-based (SnO{sub 2}) sorbent as the first sorbent and zinc ferrite (or zinc titanate) as a second sorbent to remove H{sub 2}S to very low concentrations. The process converts the sulfides from both sorbents to elemental sulfur, a commercial product which is easy to store and transport. The object of this phase is to develop chemically active, high sulfur loadings, and durable stannic oxide sorbents and to demonstrate the process at the bench scale.},
doi = {},
url = {https://www.osti.gov/biblio/140668}, journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jun 01 00:00:00 EDT 1993},
month = {Tue Jun 01 00:00:00 EDT 1993}
}

Conference:
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