Electrochemically Controlled Ion-exchange Property of Carbon Nanotubes/Polypyrrole Nanocomposite in Various Electrolyte Solutions

Choi, Daiwon; Zhu, Chengzhou; Fu, Shaofang; Du, Dan; Engelhard, Mark H.; Lin, Yuehe

doi:10.1002/elan.201600466

Title: Electrochemically Controlled Ion-exchange Property of Carbon Nanotubes/Polypyrrole Nanocomposite in Various Electrolyte Solutions

Journal Article · Thu Sep 15 00:00:00 EDT 2016 · Electroanalysis

DOI:https://doi.org/10.1002/elan.201600466· OSTI ID:1372965

Choi, Daiwon ^[1]; Zhu, Chengzhou ^[2]; Fu, Shaofang ^[2]; Du, Dan ^[2]; Engelhard, Mark H. ^[1]; Lin, Yuehe ^[3]

Pacific Northwest National Laboratory, 902 Battelle Boulevard P.O. Box 999 Richland WA 99352 USA
School of Mechanical and Materials Engineering, Washington State University, Pullman, Washington 99164-2920 United States
Pacific Northwest National Laboratory, 902 Battelle Boulevard P.O. Box 999 Richland WA 99352 USA; School of Mechanical and Materials Engineering, Washington State University, Pullman, Washington 99164-2920 United States

The electrochemically controlled ion-exchange properties of multi-wall carbon nanotube (MWNT)/electronically conductive polypyrrole (PPy) polymer composite in the various electrolyte solutions have been investigated. The ion-exchange behavior, rate and capacity of the electrochemically deposited polypyrrole with and without carbon nanotube (CNT) were compared and characterized using cyclic voltammetry (CV), chronoamperometry (CA), electrochemical quartz crystal microbalance (EQCM), X-ray photoelectron spectroscopy (XPS) and scanning electron microscopy (SEM). It has been found that the presence of carbon nanotube backbone resulted in improvement in ion-exchange rate, stability of polypyrrole, and higher anion loading capacity per PPy due to higher surface area, electronic conductivity, porous structure of thin film, and thinner film thickness providing shorter diffusion path. Chronoamperometric studies show that electrically switched anion exchange could be completed more than 10 times faster than pure PPy thin film. The anion selectivity of CNT/PPy film is demonstrated using X-ray photoelectron spectroscopy (XPS).

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States). Environmental Molecular Sciences Laboratory (EMSL)

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER)

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1372965

Report Number(s):: PNNL-SA-120743; 48877; TE1400000

Journal Information:: Electroanalysis, Vol. 29, Issue 3; ISSN 1040-0397

Publisher:: Wiley

Country of Publication:: United States

Language:: English

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