Correlation of the fragility of metallic liquids with the high temperature structure, volume, and cohesive energy

Gangopadhyay, A. K.; Pueblo, C. E.; Dai, R.; Johnson, M. L.; Ashcraft, R.; Van Hoesen, D.; Sellers, M.; Kelton, K. F.

doi:10.1063/1.4981011

Title: Correlation of the fragility of metallic liquids with the high temperature structure, volume, and cohesive energy

Journal Article · Fri Apr 21 00:00:00 EDT 2017 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/1.4981011· OSTI ID:1356407

Gangopadhyay, A. K. ^[1];

^[1]; Dai, R. ^[1];

^[1]; Ashcraft, R. ^[1];

^[1];

^[1]; Kelton, K. F. ^[1]

Washington Univ., St. Louis, MO (United States). Dept. of Physics and Inst. of Materials Science & Engineering

In this work, the thermal expansion coefficients, structure factors, and viscosities of twenty-five equilibrium and supercooled metallic liquids have been measured using an electrostatic levitation (ESL) facility. The structure factor was measured at the Advanced Photon Source, Argonne, using the ESL. A clear connection between liquid fragility and structural and volumetric changes at high temperatures is established; the observed changes are larger for the more fragile liquids. It is also demonstrated that the fragility of metallic liquids is determined to a large extent by the cohesive energy and is, therefore, predictable. These results are expected to provide useful guidance in the future design of metallic glasses.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: National Aeronautics and Space Administration (NASA); National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; NNX10AU19G; NNX16AB52G; DMR 15-06553; DMR 12-06707

OSTI ID:: 1356407

Journal Information:: Journal of Chemical Physics, Vol. 146, Issue 15; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: ENGLISH

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Cited by: 20 works

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