Star PolyMOCs with Diverse Structures, Dynamics, and Functions by Three-Component Assembly

Wang, Yufeng; Gu, Yuwei; Keeler, Eric G.; Park, Jiwon V.; Griffin, Robert G.; Johnson, Jeremiah A.

doi:10.1002/anie.201609261

Title: Star PolyMOCs with Diverse Structures, Dynamics, and Functions by Three-Component Assembly

Journal Article · Mon Dec 05 00:00:00 EST 2016 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201609261· OSTI ID:1346233

^[1]; Gu, Yuwei ^[2]; Keeler, Eric G. ^[3]; Park, Jiwon V. ^[2]; Griffin, Robert G. ^[3];

^[2]

Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue Cambridge MA USA; Department of Chemistry, the University of Hong Kong, Pokfulam Road Hong Kong SAR China
Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue Cambridge MA USA
Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue Cambridge MA USA; Francis Bitter Magnet Laboratory, Massachusetts Institute of Technology, 77 Massachusetts Avenue Cambridge MA USA

We report star polymer metal–organic cage (polyMOC) materials whose structures, mechanical properties, functionalities, and dynamics can all be precisely tailored through a simple three-component assembly strategy. The star polyMOC network is composed of tetra-arm star polymers functionalized with ligands on the chain ends, small molecule ligands, and palladium ions; polyMOCs are formed via metal–ligand coordination and thermal annealing. The ratio of small molecule ligands to polymer-bound ligands determines the connectivity of the MOC junctions and the network structure. The use of large M12L24 MOCs enables great flexibility in tuning this ratio, which provides access to a rich spectrum of material properties including tunable moduli and relaxation dynamics.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)

Sponsoring Organization:: USDOE Office of Science (SC)

OSTI ID:: 1346233

Journal Information:: Angewandte Chemie (International Edition), Vol. 56, Issue 1; ISSN 1433-7851

Publisher:: Wiley

Country of Publication:: United States

Language:: ENGLISH

References (50)

Hydrogel: Preparation, characterization, and applications: A review Ahmed, Enas M. Journal of Advanced Research, Vol. 6, Issue 2 https://doi.org/10.1016/j.jare.2013.07.006	journal	March 2015
Organogels and their use in drug delivery — A review Vintiloiu, Anda; Leroux, Jean-Christophe Journal of Controlled Release, Vol. 125, Issue 3 https://doi.org/10.1016/j.jconrel.2007.09.014	journal	February 2008
Toughening Elastomers with Sacrificial Bonds and Watching Them Break Ducrot, E.; Chen, Y.; Bulters, M. Science, Vol. 344, Issue 6180 https://doi.org/10.1126/science.1248494	journal	April 2014
Design and applications of interpenetrating polymer network hydrogels. A review Dragan, Ecaterina Stela Chemical Engineering Journal, Vol. 243 https://doi.org/10.1016/j.cej.2014.01.065	journal	May 2014
Mechanically Stiff Nanocomposite Hydrogels at Ultralow Nanoparticle Content Jaiswal, Manish K.; Xavier, Janet R.; Carrow, James K. ACS Nano, Vol. 10, Issue 1 https://doi.org/10.1021/acsnano.5b03918	journal	December 2015
Silica-Like Malleable Materials from Permanent Organic Networks Montarnal, D.; Capelot, M.; Tournilhac, F. Science, Vol. 334, Issue 6058 https://doi.org/10.1126/science.1212648	journal	November 2011
A Thermally Re-mendable Cross-Linked Polymeric Material Chen, Xiangxu; Dam, Matheus A.; Ono, Kanji Science, Vol. 295, Issue 5560, p. 1698-1702 https://doi.org/10.1126/science.1065879	journal	March 2002
Self-Assembly of Discrete Cyclic Nanostructures Mediated by Transition Metals Leininger, Stefan; Olenyuk, Bogdan; Stang, Peter J. Chemical Reviews, Vol. 100, Issue 3 https://doi.org/10.1021/cr9601324	journal	March 2000
Multicomponent metal–ligand self-assembly Sun, Wei-Yin; Yoshizawa, Michito; Kusukawa, Takahiro Current Opinion in Chemical Biology, Vol. 6, Issue 6 https://doi.org/10.1016/S1367-5931(02)00358-7	journal	December 2002
From supramolecular chemistry towards constitutional dynamic chemistry and adaptive chemistry Lehn, Jean-Marie Chem. Soc. Rev., Vol. 36, Issue 2 https://doi.org/10.1039/B616752G	journal	January 2007
Metal–organic container molecules through subcomponent self-assembly Ronson, Tanya K.; Zarra, Salvatore; Black, Samuel P. Chemical Communications, Vol. 49, Issue 25 https://doi.org/10.1039/c2cc36363a	journal	January 2013
Giant hollow MnL2n spherical complexes: structure, functionalisation and applications Harris, Kate; Fujita, Daishi; Fujita, Makoto Chemical Communications, Vol. 49, Issue 60 https://doi.org/10.1039/c3cc43191f	journal	January 2013
Supramolecular Coordination: Self-Assembly of Finite Two- and Three-Dimensional Ensembles Chakrabarty, Rajesh; Mukherjee, Partha Sarathi; Stang, Peter J. Chemical Reviews, Vol. 111, Issue 11, p. 6810-6918 https://doi.org/10.1021/cr200077m	journal	November 2011
Recent Developments in the Preparation and Chemistry of Metallacycles and Metallacages via Coordination Cook, Timothy R.; Stang, Peter J. Chemical Reviews, Vol. 115, Issue 15 https://doi.org/10.1021/cr5005666	journal	March 2015
Biomedical and Biochemical Applications of Self-Assembled Metallacycles and Metallacages Cook, Timothy R.; Vajpayee, Vaishali; Lee, Min Hyung Accounts of Chemical Research, Vol. 46, Issue 11 https://doi.org/10.1021/ar400010v	journal	June 2013
Self-Assembly, Symmetry, and Molecular Architecture: Coordination as the Motif in the Rational Design of Supramolecular Metallacyclic Polygons and Polyhedra Stang, Peter J.; Olenyuk, Bogdan Accounts of Chemical Research, Vol. 30, Issue 12 https://doi.org/10.1021/ar9602011	journal	December 1997
Stimuli-Responsive Metal–Ligand Assemblies McConnell, Anna J.; Wood, Christopher S.; Neelakandan, Prakash P. Chemical Reviews, Vol. 115, Issue 15 https://doi.org/10.1021/cr500632f	journal	April 2015
Construction, Substitution, and Sorting of Metallo-organic Structures via Subcomponent Self-Assembly Nitschke, Jonathan R. Accounts of Chemical Research, Vol. 40, Issue 2 https://doi.org/10.1021/ar068185n	journal	February 2007
Building on architectural principles for three-dimensional metallosupramolecular construction Smulders, Maarten M. J.; Riddell, Imogen A.; Browne, Colm Chem. Soc. Rev., Vol. 42, Issue 4 https://doi.org/10.1039/C2CS35254K	journal	January 2013
Proton-Mediated Chemistry and Catalysis in a Self-Assembled Supramolecular Host Pluth, Michael D.; Bergman, Robert G.; Raymond, Kenneth N. Accounts of Chemical Research, Vol. 42, Issue 10 https://doi.org/10.1021/ar900118t	journal	October 2009
Square-Planar Pd(II), Pt(II), and Au(III) Terpyridine Complexes: Their Syntheses, Physical Properties, Supramolecular Constructs, and Biomedical Activities Eryazici, Ibrahim; Moorefield, Charles N.; Newkome, George R. Chemical Reviews, Vol. 108, Issue 6 https://doi.org/10.1021/cr0781059	journal	June 2008
Two-stage directed self-assembly of a cyclic [3]catenane Wood, Christopher S.; Ronson, Tanya K.; Belenguer, Ana M. Nature Chemistry, Vol. 7, Issue 4 https://doi.org/10.1038/nchem.2205	journal	March 2015
Encapsulation, storage and controlled release of sulfur hexafluoride from a metal–organic capsule Riddell, Imogen A.; Smulders, Maarten M. J.; Clegg, Jack K. Chem. Commun., Vol. 47, Issue 1 https://doi.org/10.1039/C0CC02573A	journal	January 2011
A supramolecular approach to combining enzymatic and transition metal catalysis Wang, Z. Jane; Clary, Kristen N.; Bergman, Robert G. Nature Chemistry, Vol. 5, Issue 2 https://doi.org/10.1038/nchem.1531	journal	January 2013
Self- and Directed Assembly of Hexaruthenium Macrocycles Newkome, George R.; Cho, Tae Joon; Moorefield, Charles N. Angewandte Chemie International Edition, Vol. 38, Issue 24 https://doi.org/10.1002/(SICI)1521-3773(19991216)38:24<3717::AID-ANIE3717>3.0.CO;2-C	journal	December 1999
Selbstorganisation und gesteuerte Organisation von Hexaruthenium-Makrocyclen Newkome, George R.; Cho, Tae Joon; Moorefield, Charles N. Angewandte Chemie, Vol. 111, Issue 24 https://doi.org/10.1002/(SICI)1521-3757(19991216)111:24<3899::AID-ANGE3899>3.0.CO;2-3	journal	December 1999
Precise Molecular Fission and Fusion: Quantitative Self-Assembly and Chemistry of a Metallo-Cuboctahedron Xie, Ting-Zheng; Guo, Kai; Guo, Zaihong Angewandte Chemie International Edition, Vol. 54, Issue 32 https://doi.org/10.1002/anie.201503609	journal	June 2015
Precise Molecular Fission and Fusion: Quantitative Self-Assembly and Chemistry of a Metallo-Cuboctahedron Xie, Ting-Zheng; Guo, Kai; Guo, Zaihong Angewandte Chemie, Vol. 127, Issue 32 https://doi.org/10.1002/ange.201503609	journal	June 2015
Construction of a Highly Symmetric Nanosphere via a One-Pot Reaction of a Tristerpyridine Ligand with Ru(II) Xie, Ting-Zheng; Liao, Sheng-Yun; Guo, Kai Journal of the American Chemical Society, Vol. 136, Issue 23 https://doi.org/10.1021/ja502962j	journal	May 2014
Formation of Rack- and Grid-Type Metallosupramolecular Architectures and Generation of Molecular Motion by Reversible Uncoiling of Helical Ligand Strands Stadler, Adrian-Mihail; Kyritsakas, Nathalie; Graff, Roland Chemistry - A European Journal, Vol. 12, Issue 17 https://doi.org/10.1002/chem.200501202	journal	June 2006
Dual Role for 1,2,4,5-Tetrazines in Polymer Networks: Combining Diels–Alder Reactions and Metal Coordination To Generate Functional Supramolecular Gels Kawamoto, Ken; Grindy, Scott C.; Liu, Jenny ACS Macro Letters, Vol. 4, Issue 4 https://doi.org/10.1021/acsmacrolett.5b00221	journal	April 2015
Highly branched and loop-rich gels via formation of metal–organic cages linked by polymers Zhukhovitskiy, Aleksandr V.; Zhong, Mingjiang; Keeler, Eric G. Nature Chemistry, Vol. 8, Issue 1 https://doi.org/10.1038/nchem.2390	journal	November 2015
Differentially Addressable Cavities within Metal–Organic Cage-Cross-Linked Polymeric Hydrogels Foster, Jonathan A.; Parker, Richard M.; Belenguer, Ana M. Journal of the American Chemical Society, Vol. 137, Issue 30 https://doi.org/10.1021/jacs.5b05507	journal	July 2015
Responsive Supramolecular Polymer Metallogel Constructed by Orthogonal Coordination-Driven Self-Assembly and Host/Guest Interactions Yan, Xuzhou; Cook, Timothy R.; Pollock, J. Bryant Journal of the American Chemical Society, Vol. 136, Issue 12 https://doi.org/10.1021/ja412249k	journal	March 2014
Supramolecular polymers with tunable topologies via hierarchical coordination-driven self-assembly and hydrogen bonding interfaces Yan, X.; Li, S.; Pollock, J. B. Proceedings of the National Academy of Sciences, Vol. 110, Issue 39 https://doi.org/10.1073/pnas.1307472110	journal	September 2013
Optically healable supramolecular polymers Burnworth, Mark; Tang, Liming; Kumpfer, Justin R. Nature, Vol. 472, Issue 7343, p. 334-337 https://doi.org/10.1038/nature09963	journal	April 2011
Polymer Structure Dependent Hierarchy in PolyMOC Gels Zhukhovitskiy, Aleksandr V.; Zhao, Julia; Zhong, Mingjiang Macromolecules, Vol. 49, Issue 18 https://doi.org/10.1021/acs.macromol.6b01607	journal	September 2016
Cross-Linked Supramolecular Polymer Gels Constructed from Discrete Multi-pillar[5]arene Metallacycles and Their Multiple Stimuli-Responsive Behavior Li, Zhong-Yu; Zhang, Yanyan; Zhang, Chang-Wei Journal of the American Chemical Society, Vol. 136, Issue 24 https://doi.org/10.1021/ja413047r	journal	March 2014
Construction of Smart Supramolecular Polymeric Hydrogels Cross-linked by Discrete Organoplatinum(II) Metallacycles via Post-Assembly Polymerization Zheng, Wei; Chen, Li-Jun; Yang, Guang Journal of the American Chemical Society, Vol. 138, Issue 14 https://doi.org/10.1021/jacs.6b01089	journal	March 2016
Metal–Organic Polyhedral Core as a Versatile Scaffold for Divergent and Convergent Star Polymer Synthesis Hosono, Nobuhiko; Gochomori, Mika; Matsuda, Ryotaro Journal of the American Chemical Society, Vol. 138, Issue 20 https://doi.org/10.1021/jacs.6b01758	journal	May 2016
Block Co-PolyMOCs by Stepwise Self-Assembly Wang, Yufeng; Zhong, Mingjiang; Park, Jiwon V. Journal of the American Chemical Society, Vol. 138, Issue 33 https://doi.org/10.1021/jacs.6b06712	journal	August 2016
Anomalous Self-Diffusion and Sticky Rouse Dynamics in Associative Protein Hydrogels Tang, Shengchang; Wang, Muzhou; Olsen, Bradley D. Journal of the American Chemical Society, Vol. 137, Issue 11 https://doi.org/10.1021/jacs.5b00722	journal	March 2015
Counting primary loops in polymer gels Zhou, H.; Woo, J.; Cok, A. M. Proceedings of the National Academy of Sciences, Vol. 109, Issue 47 https://doi.org/10.1073/pnas.1213169109	journal	November 2012
Quantifying the impact of molecular defects on polymer network elasticity Zhong, M.; Wang, R.; Kawamoto, K. Science, Vol. 353, Issue 6305 https://doi.org/10.1126/science.aag0184	journal	September 2016
Remarkable Stabilization of M ₁₂ L ₂₄ Spherical Frameworks through the Cooperation of 48 Pd(II)−Pyridine Interactions Sato, Sota; Ishido, Yoshitaka; Fujita, Makoto Journal of the American Chemical Society, Vol. 131, Issue 17 https://doi.org/10.1021/ja900676f	journal	May 2009
Coordination-Directed Self-Assembly of M ₁₂ L ₂₄ Nanocage: Effects of Kinetic Trapping on the Assembly Process Yoneya, Makoto; Tsuzuki, Seiji; Yamaguchi, Tomohiko ACS Nano, Vol. 8, Issue 2 https://doi.org/10.1021/nn404595j	journal	January 2014
Dynamics of reversible networks Leibler, Ludwik; Rubinstein, Michael; Colby, Ralph H. Macromolecules, Vol. 24, Issue 16 https://doi.org/10.1021/ma00016a034	journal	August 1991
Reptation of living polymers: dynamics of entangled polymers in the presence of reversible chain-scission reactions Cates, M. E. Macromolecules, Vol. 20, Issue 9 https://doi.org/10.1021/ma00175a038	journal	September 1987
Synthesis and Linear Viscoelasticity of Fluorinated Hydrophobically Modified Ethoxylated Urethanes (F-HEUR) Cathébras, Nathalie; Collet, André; Viguier, Michel Macromolecules, Vol. 31, Issue 4 https://doi.org/10.1021/ma9709011	journal	February 1998
Self-Assembly of M 30 L 60 Icosidodecahedron Fujita, Daishi; Ueda, Yoshihiro; Sato, Sota Chem, Vol. 1, Issue 1 https://doi.org/10.1016/j.chempr.2016.06.007	journal	July 2016

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