Toward clean suspended CVD graphene

Yulaev, Alexander; Cheng, Guangjun; Hight Walker, Angela R.; Vlassiouk, Ivan V.; Myers, Alline; Leite, Marina S.; Kolmakov, Andrei

doi:10.1039/C6RA17360H

Title: Toward clean suspended CVD graphene

Journal Article · Fri Aug 26 00:00:00 EDT 2016 · RSC Advances

DOI:https://doi.org/10.1039/C6RA17360H· OSTI ID:1344290

Yulaev, Alexander ^[1]; Cheng, Guangjun ^[1]; Hight Walker, Angela R. ^[1]; Vlassiouk, Ivan V. ^[2]; Myers, Alline ^[1]; Leite, Marina S. ^[3]; Kolmakov, Andrei ^[1]

National Institute of Standards and Technology (NIST), Gaithersburg, MD (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Univ. of Maryland, College Park, MD (United States)

The application of suspended graphene as electron transparent supporting media in electron microscopy, vacuum electronics, and micromechanical devices requires the least destructive and maximally clean transfer from their original growth substrate to the target of interest. Here, we use thermally evaporated anthracene films as the sacrificial layer for graphene transfer onto an arbitrary substrate. We show that clean suspended graphene can be achieved via desorbing the anthracene layer at temperatures in the 100 °C to 150 °C range, followed by two sequential annealing steps for the final cleaning, using a Pt catalyst and activated carbon. The cleanliness of the suspended graphene membranes was analyzed employing the high surface sensitivity of low energy scanning electron microscopy and X-ray photoelectron spectroscopy. A quantitative comparison with two other commonly used transfer methods revealed the superiority of the anthracene approach to obtain a larger area of clean, suspended CVD graphene. Lastly, our graphene transfer method based on anthracene paves the way for integrating cleaner graphene in various types of complex devices, including the ones that are heat and humidity sensitive.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1344290

Journal Information:: RSC Advances, Vol. 6, Issue 87; ISSN 2046-2069

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 19 works

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References (41)

Functionalized graphite nanoplatelets/epoxy resin nanocomposites with high thermal conductivity Gu, Junwei; Yang, Xutong; Lv, Zhaoyuan International Journal of Heat and Mass Transfer, Vol. 92 https://doi.org/10.1016/j.ijheatmasstransfer.2015.08.081	journal	January 2016
Migration and Localization of Metal Atoms on Strained Graphene Cretu, Ovidiu; Krasheninnikov, Arkady V.; Rodríguez-Manzo, Julio A. Physical Review Letters, Vol. 105, Issue 19 https://doi.org/10.1103/PhysRevLett.105.196102	journal	November 2010
Drop-Casted Self-Assembling Graphene Oxide Membranes for Scanning Electron Microscopy on Wet and Dense Gaseous Samples Krueger, Mark; Berg, Shannon; Stone, D’Arcy ACS Nano, Vol. 5, Issue 12 https://doi.org/10.1021/nn204287g	journal	November 2011
Large-Area Graphene Single Crystals Grown by Low-Pressure Chemical Vapor Deposition of Methane on Copper Li, Xuesong; Magnuson, Carl W.; Venugopal, Archana Journal of the American Chemical Society, Vol. 133, Issue 9, p. 2816-2819 https://doi.org/10.1021/ja109793s	journal	March 2011
Graphene Annealing: How Clean Can It Be? Lin, Yung-Chang; Lu, Chun-Chieh; Yeh, Chao-Huei Nano Letters, Vol. 12, Issue 1, p. 414-419 https://doi.org/10.1021/nl203733r	journal	December 2011
Role of Hydrogen in Chemical Vapor Deposition Growth of Large Single-Crystal Graphene Vlassiouk, Ivan; Regmi, Murari; Fulvio, Pasquale ACS Nano, Vol. 5, Issue 7, p. 6069-6076 https://doi.org/10.1021/nn201978y	journal	July 2011
A new examination of secondary electron yield data Lin, Yinghong; Joy, David C. Surface and Interface Analysis, Vol. 37, Issue 11 https://doi.org/10.1002/sia.2107	journal	January 2005
Toward Intrinsic Graphene Surfaces: A Systematic Study on Thermal Annealing and Wet-Chemical Treatment of SiO ₂ -Supported Graphene Devices Cheng, Zengguang; Zhou, Qiaoyu; Wang, Chenxuan Nano Letters, Vol. 11, Issue 2 https://doi.org/10.1021/nl103977d	journal	February 2011
Surface analysis and angular distributions in x-ray photoelectron spectroscopy Fadley, C. S.; Baird, R. J.; Siekhaus, W. Journal of Electron Spectroscopy and Related Phenomena, Vol. 4, Issue 2 https://doi.org/10.1016/0368-2048(74)90001-2	journal	January 1974
A direct transfer of layer-area graphene Regan, William; Alem, Nasim; Alemán, Benjamín Applied Physics Letters, Vol. 96, Issue 11 https://doi.org/10.1063/1.3337091	journal	March 2010
The effect of chemical residues on the physical and electrical properties of chemical vapor deposited graphene transferred to SiO ₂ Pirkle, A.; Chan, J.; Venugopal, A. Applied Physics Letters, Vol. 99, Issue 12 https://doi.org/10.1063/1.3643444	journal	September 2011
Graphene transfer: key for applications Kang, Junmo; Shin, Dolly; Bae, Sukang Nanoscale, Vol. 4, Issue 18 https://doi.org/10.1039/c2nr31317k	journal	January 2012
Very low energy electron microscopy of graphene flakes: VERY LOW ENERGY ELECTRON MICROSCOPY OF GRAPHENE FLAKES MikmekovÁ, E.; Bouyanfif, H.; Lejeune, M. Journal of Microscopy, Vol. 251, Issue 2 https://doi.org/10.1111/jmi.12049	journal	May 2013
Three-dimensional electron microscopy simulation with the CASINO Monte Carlo software Demers, Hendrix; Poirier-Demers, Nicolas; Couture, Alexandre Réal Scanning, Vol. 33, Issue 3 https://doi.org/10.1002/sca.20262	journal	May 2011
Graphene transfer with reduced residue Her, Michael; Beams, Ryan; Novotny, Lukas Physics Letters A, Vol. 377, Issue 21-22 https://doi.org/10.1016/j.physleta.2013.04.015	journal	September 2013
Vapor Pressures and Enthalpies of Sublimation of Polycyclic Aromatic Hydrocarbons and Their Derivatives Oja, Vahur; Suuberg, Eric M. Journal of Chemical & Engineering Data, Vol. 43, Issue 3 https://doi.org/10.1021/je970222l	journal	May 1998
Ultraclean freestanding graphene by platinum-metal catalysis Longchamp, Jean-Nicolas; Escher, Conrad; Fink, Hans-Werner Journal of Vacuum Science & Technology B, Nanotechnology and Microelectronics: Materials, Processing, Measurement, and Phenomena, Vol. 31, Issue 2 https://doi.org/10.1116/1.4793746	journal	March 2013
Photoelectron spectroscopy of wet and gaseous samples through graphene membranes Kraus, Jürgen; Reichelt, Robert; Günther, Sebastian Nanoscale, Vol. 6, Issue 23 https://doi.org/10.1039/C4NR03561E	journal	January 2014
Grains and grain boundaries in single-layer graphene atomic patchwork quilts Huang, Pinshane Y.; Ruiz-Vargas, Carlos S.; van der Zande, Arend M. Nature, Vol. 469, Issue 7330, p. 389-392 https://doi.org/10.1038/nature09718	journal	January 2011
Metal-catalyzed etching of graphene governed by metal–carbon interactions: A comparison of Fe and Cu Cheng, Guangjun; Calizo, Irene; Hight Walker, Angela R. Carbon, Vol. 81 https://doi.org/10.1016/j.carbon.2014.10.005	journal	January 2015
Detection of individual gas molecules adsorbed on graphene Schedin, F.; Geim, A. K.; Morozov, S. V. Nature Materials, Vol. 6, Issue 9, p. 652-655 https://doi.org/10.1038/nmat1967	journal	July 2007
Large-scale pattern growth of graphene films for stretchable transparent electrodes Kim, Keun Soo; Zhao, Yue; Jang, Houk Nature, Vol. 457, Issue 7230 https://doi.org/10.1038/nature07719	journal	January 2009
Effect of airborne contaminants on the wettability of supported graphene and graphite Li, Zhiting; Wang, Yongjin; Kozbial, Andrew Nature Materials, Vol. 12, Issue 10 https://doi.org/10.1038/nmat3709	journal	July 2013
High-Resolution EM of Colloidal Nanocrystal Growth Using Graphene Liquid Cells Yuk, Jong Min; Park, Jungwon; Ercius, Peter Science, Vol. 336, Issue 6077 https://doi.org/10.1126/science.1217654	journal	April 2012
Transferring and Identification of Single- and Few-Layer Graphene on Arbitrary Substrates Reina, Alfonso; Son, Hyungbin; Jiao, Liying The Journal of Physical Chemistry C, Vol. 112, Issue 46 https://doi.org/10.1021/jp807380s	journal	October 2008
Repeated growth and bubbling transfer of graphene with millimetre-size single-crystal grains using platinum Gao, Libo; Ren, Wencai; Xu, Huilong Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms1702	journal	January 2012
Low-energy electron transmission imaging of clusters on free-standing graphene Longchamp, Jean-Nicolas; Latychevskaia, Tatiana; Escher, Conrad Applied Physics Letters, Vol. 101, Issue 11 https://doi.org/10.1063/1.4752717	journal	September 2012
Atomic Structure of Graphene on SiO₂ Ishigami, Masa; Chen, J. H.; Cullen, W. G. Nano Letters, Vol. 7, Issue 6, p. 1643-1648 https://doi.org/10.1021/nl070613a	journal	June 2007
Boron nitride substrates for high-quality graphene electronics Dean, C. R.; Young, A. F.; Meric, I. Nature Nanotechnology, Vol. 5, Issue 10, p. 722-726 https://doi.org/10.1038/nnano.2010.172	journal	August 2010
Annealing free, clean graphene transfer using alternative polymer scaffolds Wood, Joshua D.; Doidge, Gregory P.; Carrion, Enrique A. Nanotechnology, Vol. 26, Issue 5 https://doi.org/10.1088/0957-4484/26/5/055302	journal	January 2015
Large-Area Synthesis of High-Quality and Uniform Graphene Films on Copper Foils Li, X.; Cai, W.; An, J. Science, Vol. 324, Issue 5932, p. 1312-1314 https://doi.org/10.1126/science.1171245	journal	May 2009
Processes for non-destructive transfer of graphene: widening the bottleneck for industrial scale production Zaretski, Aliaksandr V.; Lipomi, Darren J. Nanoscale, Vol. 7, Issue 22 https://doi.org/10.1039/C5NR01777G	journal	January 2015
‘Bubble-Free’ Electrochemical Delamination of CVD Graphene Films Cherian, Christie Thomas; Giustiniano, Francesco; Martin-Fernandez, Iñigo Small, Vol. 11, Issue 2 https://doi.org/10.1002/smll.201402024	journal	September 2014
Interaction of Metals with Suspended Graphene Observed by Transmission Electron Microscopy Zan, Recep; Bangert, Ursel; Ramasse, Quentin The Journal of Physical Chemistry Letters, Vol. 3, Issue 7 https://doi.org/10.1021/jz201653g	journal	March 2012
Transfer of CVD-Grown Monolayer Graphene onto Arbitrary Substrates Suk, Ji Won; Kitt, Alexander; Magnuson, Carl W. ACS Nano, Vol. 5, Issue 9 https://doi.org/10.1021/nn201207c	journal	August 2011
Dry-cleaning of graphene Algara-Siller, Gerardo; Lehtinen, Ossi; Turchanin, Andrey Applied Physics Letters, Vol. 104, Issue 15 https://doi.org/10.1063/1.4871997	journal	April 2014
Electromechanical Resonators from Graphene Sheets Bunch, J. S.; van der Zande, A. M.; Verbridge, S. S. Science, Vol. 315, Issue 5811 https://doi.org/10.1126/science.1136836	journal	January 2007
A facile process for soak-and-peel delamination of CVD graphene from substrates using water Gupta, Priti; Dongare, Pratiksha D.; Grover, Sameer Scientific Reports, Vol. 4, Issue 1 https://doi.org/10.1038/srep03882	journal	January 2014
Roll-to-roll production of 30-inch graphene films for transparent electrodes Bae, Sukang; Kim, Hyeongkeun; Lee, Youngbin Nature Nanotechnology, Vol. 5, Issue 8, p. 574-578 https://doi.org/10.1038/nnano.2010.132	journal	June 2010
Transfer of Large-Area Graphene Films for High-Performance Transparent Conductive Electrodes Li, Xuesong; Zhu, Yanwu; Cai, Weiwei Nano Letters, Vol. 9, Issue 12 https://doi.org/10.1021/nl902623y	journal	December 2009
Simulation of electron spectra for surface analysis (SESSA): a novel software tool for quantitative Auger-electron spectroscopy and X-ray photoelectron spectroscopy Smekal, Werner; Werner, Wolfgang S. M.; Powell, Cedric J. Surface and Interface Analysis, Vol. 37, Issue 11 https://doi.org/10.1002/sia.2097	journal	January 2005

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