U.S. Department of EnergyOffice of Scientific and Technical Information
In situ characterization of charge rate dependent stress and structure changes in V2O5 cathode prepared by atomic layer deposition
Abstract
Here, the insertion/extraction of lithium into/from various host materials is the basic process by which lithium-ion batteries reversible store charge. This process is generally accompanied by strain in the host material, inducing stress which can lead to capacity loss. Therefore, understanding of both the structural changes and the associated stress – investigated almost exclusively separate to date – is a critical factor for developing high-performance batteries. Here, we report an in situ method, which utilizes Raman spectroscopy in parallel with optical interferometry to study effects of varying charging rates (C-rates) on the structure and stress in a V2O5 thin film cathode. Abrupt stress changes at specific crystal phase transitions in the Li—V—O system are observed and the magnitude of the stress changes with the amount of lithium inserted into the electrode are correlated. A linear increase in the stress as a function of x in LixV2O5 is observed, indicating that C-rate does not directly contribute to larger intercalation stress. However, a more rapid increase in disorder within the LixV2O5 layers is correlated with higher C-rate. Ultimately, these experiments demonstrate how the simultaneous stress/Raman in situ approach can be utilized as a characterization platform for investigating various critical factors affecting lithium-ionmore »
- Authors:
-
- Univ. of Maryland, College Park, MD (United States)
- Univ. of Maryland, College Park, MD (United States); The Johns Hopkins Univ., Laurel, MD (United States)
- Sandia National Lab. (SNL-CA), Livermore, CA (United States)
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-CA), Livermore, CA (United States); Energy Frontier Research Centers (EFRC) (United States). Nanostructures for Electrical Energy Storage (NEES)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1343624
- Alternate Identifier(s):
- OSTI ID: 1410839
- Report Number(s):
- SAND-2017-0811J
Journal ID: ISSN 0378-7753; 650724
- Grant/Contract Number:
- AC04-94AL85000; SC0001160; DESC0001160
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Journal of Power Sources
- Additional Journal Information:
- Journal Volume: 340; Journal Issue: C; Journal ID: ISSN 0378-7753
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; Lithium-ion battery; vanadium oxide; charge rates; in situ; Raman spectroscopy; stress
Citation Formats
Jung, Hyun, Gerasopoulos, Konstantinos, Talin, Albert Alec, and Ghodssi, Reza. In situ characterization of charge rate dependent stress and structure changes in V2O5 cathode prepared by atomic layer deposition. United States: N. p., 2016.
Web. doi:10.1016/j.jpowsour.2016.11.035.
Jung, Hyun, Gerasopoulos, Konstantinos, Talin, Albert Alec, & Ghodssi, Reza. In situ characterization of charge rate dependent stress and structure changes in V2O5 cathode prepared by atomic layer deposition. United States. https://doi.org/10.1016/j.jpowsour.2016.11.035
Jung, Hyun, Gerasopoulos, Konstantinos, Talin, Albert Alec, and Ghodssi, Reza. 2016.
"In situ characterization of charge rate dependent stress and structure changes in V2O5 cathode prepared by atomic layer deposition". United States. https://doi.org/10.1016/j.jpowsour.2016.11.035. https://www.osti.gov/servlets/purl/1343624.
@article{osti_1343624,
title = {In situ characterization of charge rate dependent stress and structure changes in V2O5 cathode prepared by atomic layer deposition},
author = {Jung, Hyun and Gerasopoulos, Konstantinos and Talin, Albert Alec and Ghodssi, Reza},
abstractNote = {Here, the insertion/extraction of lithium into/from various host materials is the basic process by which lithium-ion batteries reversible store charge. This process is generally accompanied by strain in the host material, inducing stress which can lead to capacity loss. Therefore, understanding of both the structural changes and the associated stress – investigated almost exclusively separate to date – is a critical factor for developing high-performance batteries. Here, we report an in situ method, which utilizes Raman spectroscopy in parallel with optical interferometry to study effects of varying charging rates (C-rates) on the structure and stress in a V2O5 thin film cathode. Abrupt stress changes at specific crystal phase transitions in the Li—V—O system are observed and the magnitude of the stress changes with the amount of lithium inserted into the electrode are correlated. A linear increase in the stress as a function of x in LixV2O5 is observed, indicating that C-rate does not directly contribute to larger intercalation stress. However, a more rapid increase in disorder within the LixV2O5 layers is correlated with higher C-rate. Ultimately, these experiments demonstrate how the simultaneous stress/Raman in situ approach can be utilized as a characterization platform for investigating various critical factors affecting lithium-ion battery performance.},
doi = {10.1016/j.jpowsour.2016.11.035},
url = {https://www.osti.gov/biblio/1343624},
journal = {Journal of Power Sources},
issn = {0378-7753},
number = C,
volume = 340,
place = {United States},
year = {Tue Nov 22 00:00:00 EST 2016},
month = {Tue Nov 22 00:00:00 EST 2016}
}
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Cited by: 9 works
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Figure 1: MEMS optical sensor geometry. (a) 3D schematic of MEMS optical sensor showing array of circular membranes. (b) Cross-section diagrams of a single membrane; shallow optical cavity at the top and deep battery cavity below.
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Works referencing / citing this record:
Interfacial Incompatibility and Internal Stresses in All‐Solid‐State Lithium Ion Batteries
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Real-time monitoring of stress development during electrochemical cycling of electrode materials for Li-ion batteries: overview and perspectives
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Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.