Hyper-crosslinked cyclodextrin porous polymer: An efficient CO2 capturing material with tunable porosity

Meng, Bo; Li, Haiyang; Mahurin, Shannon Mark; Liu, Honglai; Dai, Sheng

doi:10.1039/C6RA18307G

Title: Hyper-crosslinked cyclodextrin porous polymer: An efficient CO₂ capturing material with tunable porosity

Journal Article · Fri Nov 11 00:00:00 EST 2016 · RSC Advances

DOI:https://doi.org/10.1039/C6RA18307G· OSTI ID:1341581

Meng, Bo ^[1]; Li, Haiyang ^[2]; Mahurin, Shannon Mark ^[2]; Liu, Honglai ^[3]; Dai, Sheng ^[2]

Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
East China Univ. of Science and Technology, Shanghai (China)

We designed and synthesized the cyclodextrin (CD)-based hyper-crosslinked porous polymers (HCPPs) for selective CO₂ adsorption and storage. We also explored the effect of monomer size on micropore formation, and determined a feasible way to tailor the porosity of the materials during the hyper-crosslinking process.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1341581

Journal Information:: RSC Advances, Vol. 6, Issue 111; ISSN 2046-2069

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 16 works

Citation information provided by
Web of Science

References (24)

Hierarchically Porous Polymers from Hyper-cross-linked Block Polymer Precursors Seo, Myungeun; Kim, Soobin; Oh, Jaehoon Journal of the American Chemical Society, Vol. 137, Issue 2 https://doi.org/10.1021/ja511581w	journal	January 2015
Insights into the Asymmetric Heterogeneous Catalysis in Porous Organic Polymers: Constructing A TADDOL-Embedded Chiral Catalyst for Studying the Structure-Activity Relationship ^[ ^] An, Wan-Kai; Han, Man-Yi; Wang, Chang-An Chemistry - A European Journal, Vol. 20, Issue 35 https://doi.org/10.1002/chem.201403002	journal	July 2014
Cyclodextrin-Functionalized Hierarchical Porous Architectures for High-Throughput Capture and Release of Organic Pollutants from Wastewater Schofield, W. C. E.; Bain, C. D.; Badyal, J. P. S. Chemistry of Materials, Vol. 24, Issue 9 https://doi.org/10.1021/cm300552k	journal	April 2012
Strong and Reversible Binding of Carbon Dioxide in a Green Metal–Organic Framework Gassensmith, Jeremiah J.; Furukawa, Hiroyasu; Smaldone, Ronald A. Journal of the American Chemical Society, Vol. 133, Issue 39, p. 15312-15315 https://doi.org/10.1021/ja206525x	journal	October 2011
A Luminescent Hypercrosslinked Conjugated Microporous Polymer for Efficient Removal and Detection of Mercury Ions Xiang, Lu; Zhu, Yunlong; Gu, Shuai Macromolecular Rapid Communications, Vol. 36, Issue 17 https://doi.org/10.1002/marc.201500159	journal	June 2015
Hypercrosslinked Aromatic Heterocyclic Microporous Polymers: A New Class of Highly Selective CO ₂ Capturing Materials Luo, Yali; Li, Buyi; Wang, Wei Advanced Materials, Vol. 24, Issue 42 https://doi.org/10.1002/adma.201202447	journal	September 2012
Research Progress in Hypercrosslinked Microporous Organic Polymers Tan, Liangxiao; Tan, Bien Acta Chimica Sinica, Vol. 73, Issue 6 https://doi.org/10.6023/A15020096	journal	January 2015
Chemical functionalization strategies for carbon dioxide capture in microporous organic polymers: CO Dawson, Robert; Cooper, Andrew I.; Adams, Dave J. Polymer International, Vol. 62, Issue 3 https://doi.org/10.1002/pi.4407	journal	January 2013
Metal-free and Scalable Synthesis of Porous Hyper-cross-linked Polymers: Towards Applications in Liquid-Phase Adsorption Schute, Kai; Rose, Marcus ChemSusChem, Vol. 8, Issue 20 https://doi.org/10.1002/cssc.201500829	journal	August 2015
Formation of Microporosity in Hyper-Cross-Linked Polymers Abbott, Lauren J.; Colina, Coray M. Macromolecules, Vol. 47, Issue 15 https://doi.org/10.1021/ma500579x	journal	July 2014
Recent Development of Hypercrosslinked Microporous Organic Polymers Xu, Shujun; Luo, Yali; Tan, Bien Macromolecular Rapid Communications, Vol. 34, Issue 6 https://doi.org/10.1002/marc.201200788	journal	January 2013
Structure–Property Relationships in Amorphous Microporous Polymers Bonakala, Satyanarayana; Balasubramanian, Sundaram The Journal of Physical Chemistry B, Vol. 120, Issue 3 https://doi.org/10.1021/acs.jpcb.5b08842	journal	January 2016
Carbohydrate based hyper-crosslinked organic polymers with –OH functional groups for CO ₂ separation Li, Haiying; Meng, Bo; Mahurin, Shannon M. Journal of Materials Chemistry A, Vol. 3, Issue 42 https://doi.org/10.1039/C5TA03213J	journal	January 2015
The cost-effective synthesis of furan- and thienyl-based microporous polyaminals for adsorption of gases and organic vapors Li, Guiyang; Zhang, Biao; Yan, Jun Chemical Communications, Vol. 52, Issue 6 https://doi.org/10.1039/C5CC08195E	journal	January 2016
A new hypercrosslinked supermicroporous polymer, with scope for sulfonation, and its catalytic potential for the efficient synthesis of biodiesel at room temperature Bhunia, Subhajit; Banerjee, Biplab; Bhaumik, Asim Chemical Communications, Vol. 51, Issue 24 https://doi.org/10.1039/C4CC09872B	journal	January 2015
Hyper-crosslinked β-cyclodextrin porous polymer: an adsorption-facilitated molecular catalyst support for transformation of water-soluble aromatic molecules Li, Haiying; Meng, Bo; Chai, Song-Hai Chemical Science, Vol. 7, Issue 2 https://doi.org/10.1039/C5SC04034E	journal	January 2016
Nanoporous organic polymer networks Dawson, Robert; Cooper, Andrew I.; Adams, Dave J. Progress in Polymer Science, Vol. 37, Issue 4, p. 530-563 https://doi.org/10.1016/j.progpolymsci.2011.09.002	journal	April 2012
The effect of molecular weight on the porosity of hypercrosslinked polystyrene Ratvijitvech, Thanchanok; Barrow, Michael; Cooper, Andrew I. Polymer Chemistry, Vol. 6, Issue 41 https://doi.org/10.1039/C5PY00668F	journal	January 2015
Porous organic polymers with anchored aldehydes: a new platform for post-synthetic amine functionalization en route for enhanced CO2 adsorption properties Guillerm, Vincent; Weseliński, Łukasz J.; Alkordi, Mohamed Chemical Communications, Vol. 50, Issue 16 https://doi.org/10.1039/c3cc48228f	journal	January 2014
Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984) Sing, K. S. W. Pure and Applied Chemistry, Vol. 57, Issue 4, p. 603-619 https://doi.org/10.1351/pac198557040603	journal	January 1985
Conjugated Microporous Polymers Cooper, Andrew I. Advanced Materials, Vol. 21, Issue 12, p. 1291-1295 https://doi.org/10.1002/adma.200801971	journal	March 2009
Hypercrosslinked materials: preparation, characterisation and applications Fontanals, N.; Marcé, R. M.; Borrull, F. Polymer Chemistry, Vol. 6, Issue 41 https://doi.org/10.1039/C5PY00771B	journal	January 2015
Polycyclotrimers of 1,4-Diethynylbenzene, 2,6-Diethynylnaphthalene, and 2,6-Diethynylanthracene: Preparation and Gas Adsorption Properties Zukal, Arnošt; Slováková, Eva; Balcar, Hynek Macromolecular Chemistry and Physics, Vol. 214, Issue 18 https://doi.org/10.1002/macp.201300317	journal	July 2013
Microporous Organic Polymers with Ketal Linkages: Synthesis, Characterization, and Gas Sorption Properties Han, Ying; Zhang, Li-Min; Zhao, Yan-Chao ACS Applied Materials & Interfaces, Vol. 5, Issue 10 https://doi.org/10.1021/am400251h	journal	May 2013

Cited By (4)

Adsorption behavior and kinetics of CO ₂ on amine‐functionalized hyper‐crosslinked polymer Liu, Fenglei; Fu, Wenhao; Chen, Shuixia Journal of Applied Polymer Science, Vol. 137, Issue 12 https://doi.org/10.1002/app.48479	journal	September 2019
Highly Porous Hypercrosslinked Polymers Derived from Biobased Molecules Björnerbäck, Fredrik; Hedin, Niklas ChemSusChem, Vol. 12, Issue 4 https://doi.org/10.1002/cssc.201802681	journal	January 2019
A green sorbent for CO ₂ capture: α-cyclodextrin-based carbonate in DMSO solution Eftaiha, Ala'a F.; Qaroush, Abdussalam K.; Alsoubani, Fatima RSC Advances, Vol. 8, Issue 66 https://doi.org/10.1039/c8ra08040b	journal	January 2018
Atomistic structure generation of covalent triazine-based polymers by molecular simulation Song, Ce; Hu, Fangyuan; Meng, Zhaoliang RSC Advances, Vol. 10, Issue 8 https://doi.org/10.1039/c9ra11035f	journal	January 2020

Similar Records

Hyper-crosslinked β-cyclodextrin porous polymer: an adsorption-facilitated molecular catalyst support for transformation of water-soluble aromatic molecules

Journal Article · Fri Nov 13 00:00:00 EST 2015 · Chemical Science · OSTI ID:1341581

Li, Haiying; Meng, Bo; Chai, Song-Hai; +2 more

Amine-functionalized porous organic polymers for carbon dioxide capture

Journal Article · Wed Jun 15 00:00:00 EDT 2022 · Materials Advances · OSTI ID:1341581

Sekizkardes, Ali K.; Wang, Ping; Hoffman, James; +2 more

Fibers with Hyper‐Crosslinked Functional Porous Frameworks

Journal Article · Wed Feb 07 00:00:00 EST 2018 · Macromolecular Rapid Communications · OSTI ID:1341581

Sheng, Yujie; Chen, Qibin; Mahurin, Shannon M.; +5 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Hyper-crosslinked cyclodextrin porous polymer: An efficient CO2 capturing material with tunable porosity

Citation Formats

References (24)

Cited By (4)

Similar Records

Related Subjects

Title: Hyper-crosslinked cyclodextrin porous polymer: An efficient CO₂ capturing material with tunable porosity