Photochemical behavior of the quadruply metal-metal bonded [Tc2Cl8]2– anion in acetonitrile
Journal Article
·
· Inorganica Chimica Acta
- Hunter College of the City Univ. of New York, New York City, NY (United States); Lehman College of the City Univ. of New York, New York City, NY (United States); The Graduate Center of the City Univ. of New York, New York, NY (United States)
- Univ. of Nevada, Las Vegas, NV (United States)
- Hunter College of the City Univ. of New York, New York City, NY (United States); The Graduate Center of the City Univ. of New York, New York, NY (United States)
- Univ. of Nevada, Las Vegas, NV (United States); Argonne National Lab. (ANL), Lemont, IL (United States)
Here, the photochemical behavior of [Tc2Cl8]2– was investigated in acetonitrile. The speciation of Tc before and after irradiation at 254 nm was performed by UV-visible spectroscopy and electrospray ionization mass spectrometry (ESI-MS). Upon irradiation at 254 nm, [Tc2Cl8]2– was unstable, the scission of the Tc ≡ Tc unit occurred and the complex [TcCl4(CH3CN)2] was identified. The disappearance rate of [M2Cl8]2– (M = Tc, Re) under irradiation has been measured and was ~7.5 time faster for Tc than for Re.
- Research Organization:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Organization:
- University of Nevada–Las Vegas; National Institutes of Health (NIH); National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Grant/Contract Number:
- AC02-06CH11357; FG02-09ER16097; SC0002456
- OSTI ID:
- 1339611
- Alternate ID(s):
- OSTI ID: 1359175
- Journal Information:
- Inorganica Chimica Acta, Vol. 453, Issue C; ISSN 0020-1693
- Publisher:
- ElsevierCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Cited by: 1 work
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