Functional wettability in carbonate reservoirs

Brady, Patrick V.; Thyne, Geoffrey

doi:10.1021/acs.energyfuels.6b01895

Title: Functional wettability in carbonate reservoirs

Journal Article · Tue Oct 11 00:00:00 EDT 2016 · Energy and Fuels

DOI:https://doi.org/10.1021/acs.energyfuels.6b01895· OSTI ID:1338317

Brady, Patrick V. ^[1]; Thyne, Geoffrey ^[2]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Engineered Salinity LLC, Laramie, WY (United States)

Oil adsorbs to carbonate reservoirs indirectly through a relatively thick separating water layer, and directly to the surface through a relatively thin intervening water layer. Whereas directly sorbed oil desorbs slowly and incompletely in response to changes in reservoir conditions, indirectly sorbed oil can be rapidly desorbed by changing the chemistry of the separating water layer. The additional recovery might be as much as 30% original oil in place (OOIP) above the ~30% OOIP recovered from carbonates through reservoir depressurization (primary production) and viscous displacement (waterflooding). Electrostatic adhesive forces are the dominant control over carbonate reservoir wettability. A surface complexation model that quantifies electrostatic adhesion accurately predicts oil recovery trends for carbonates. Furthermore, the approach should therefore be useful for estimating initial wettability and designing fluids that improve oil recovery.

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Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC04-94AL85000

OSTI ID:: 1338317

Report Number(s):: SAND2016-7622J; 646430

Journal Information:: Energy and Fuels, Vol. 30, Issue 11; ISSN 0887-0624

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 113 works

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Effect of SO ₄ ⁻² ion exchanges and initial water saturation on low salinity water flooding (LSWF) in the dolomite reservoir rocks Safavi, Mir Saeid; Masihi, Mohsen; Safekordi, Ali Akbar Journal of Dispersion Science and Technology, Vol. 41, Issue 6 https://doi.org/10.1080/01932691.2019.1614026	journal	May 2019
Wettability Alteration and Enhanced Oil Recovery Induced by Proximal Adsorption of ${Na}^{+}$ , ${Cl}^{-}$ , ${Ca}^{2 +}$ , ${Mg}^{2 +}$ , and ${SO}_{4}^{2 -}$ Ions on Calcite Liu, Jian; Wani, Omar B.; Alhassan, Saeed M. Physical Review Applied, Vol. 10, Issue 3 https://doi.org/10.1103/physrevapplied.10.034064	journal	September 2018
Characterization of Organic Layer in Oil Carbonate Reservoir Rocks and its Effect on Microscale Wetting Properties Ivanova, Anastasia; Mitiurev, Nikolai; Cheremisin, Alexey Scientific Reports, Vol. 9, Issue 1 https://doi.org/10.1038/s41598-019-47139-y	journal	July 2019
Low Salinity Waterflooding in Carbonate Reservoirs: Review of Interfacial Mechanisms Derkani, Maryam; Fletcher, Ashleigh; Abdallah, Wael Colloids and Interfaces, Vol. 2, Issue 2 https://doi.org/10.3390/colloids2020020	journal	May 2018
Wettability alteration of carbonate rock by nonionic surfactants in water-based drilling fluid Kiani, M.; Ramazani SaadatAbadi, A.; Jafari Behbahani, T. International Journal of Environmental Science and Technology, Vol. 16, Issue 11 https://doi.org/10.1007/s13762-018-1932-3	journal	August 2018

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