Impact of linker engineering on the catalytic activity of metal–organic frameworks containing Pd(II)–bipyridine complexes
Abstract
A series of mixed-linker bipyridyl metal–organic framework (MOF)-supported palladium(II) catalysts were used to elucidate the electronic and steric effects of linker substitution on the activity of these catalysts in the context of Suzuki–Miyaura cross-coupling reactions. m-6,6'-Me2bpy-MOF-PdCl2 exhibited 110- and 496-fold enhancements in activity compared to nonfunctionalized m-bpy-MOF-PdCl2 and m-4,4'-Me2bpy-MOF-PdCl2, respectively. Furthermore, this result clearly demonstrates that the stereoelectronic properties of metal-binding linker units are critical to the activity of single-site organometallic catalysts in MOFs and highlights the importance of linker engineering in the design and development of efficient MOF catalysts.
- Authors:
-
- Iowa State Univ., Ames, IA (United States); Ames Lab., Ames, IA (United States)
- Iowa State Univ., Ames, IA (United States)
- Publication Date:
- Research Org.:
- Ames Laboratory (AMES), Ames, IA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1337683
- Report Number(s):
- IS-J-9087
Journal ID: ISSN 2155-5435
- Grant/Contract Number:
- AC02-07CH11358
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- ACS Catalysis
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 9; Journal ID: ISSN 2155-5435
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; bipyridyl linker; heterogeneous catalysis; isoreticular metal−organic frameworks; single-site catalyst; structure−activity relationship; Suzuki−Miyaura cross-coupling
Citation Formats
Li, Xinle, Van Zeeland, Ryan, Maligal-Ganesh, Raghu V., Pei, Yuchen, Power, Gregory, Stanley, Levi, and Huang, Wenyu. Impact of linker engineering on the catalytic activity of metal–organic frameworks containing Pd(II)–bipyridine complexes. United States: N. p., 2016.
Web. doi:10.1021/acscatal.6b01753.
Li, Xinle, Van Zeeland, Ryan, Maligal-Ganesh, Raghu V., Pei, Yuchen, Power, Gregory, Stanley, Levi, & Huang, Wenyu. Impact of linker engineering on the catalytic activity of metal–organic frameworks containing Pd(II)–bipyridine complexes. United States. https://doi.org/10.1021/acscatal.6b01753
Li, Xinle, Van Zeeland, Ryan, Maligal-Ganesh, Raghu V., Pei, Yuchen, Power, Gregory, Stanley, Levi, and Huang, Wenyu. 2016.
"Impact of linker engineering on the catalytic activity of metal–organic frameworks containing Pd(II)–bipyridine complexes". United States. https://doi.org/10.1021/acscatal.6b01753. https://www.osti.gov/servlets/purl/1337683.
@article{osti_1337683,
title = {Impact of linker engineering on the catalytic activity of metal–organic frameworks containing Pd(II)–bipyridine complexes},
author = {Li, Xinle and Van Zeeland, Ryan and Maligal-Ganesh, Raghu V. and Pei, Yuchen and Power, Gregory and Stanley, Levi and Huang, Wenyu},
abstractNote = {A series of mixed-linker bipyridyl metal–organic framework (MOF)-supported palladium(II) catalysts were used to elucidate the electronic and steric effects of linker substitution on the activity of these catalysts in the context of Suzuki–Miyaura cross-coupling reactions. m-6,6'-Me2bpy-MOF-PdCl2 exhibited 110- and 496-fold enhancements in activity compared to nonfunctionalized m-bpy-MOF-PdCl2 and m-4,4'-Me2bpy-MOF-PdCl2, respectively. Furthermore, this result clearly demonstrates that the stereoelectronic properties of metal-binding linker units are critical to the activity of single-site organometallic catalysts in MOFs and highlights the importance of linker engineering in the design and development of efficient MOF catalysts.},
doi = {10.1021/acscatal.6b01753},
url = {https://www.osti.gov/biblio/1337683},
journal = {ACS Catalysis},
issn = {2155-5435},
number = 9,
volume = 6,
place = {United States},
year = {Tue Aug 09 00:00:00 EDT 2016},
month = {Tue Aug 09 00:00:00 EDT 2016}
}
Web of Science
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