Direction to practical production of hydrogen by formic acid dehydrogenation with Cp*Ir complexes bearing imidazoline ligands
Journal Article
·
· Catalysis Science and Technology
- National Inst. of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan)
- Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.
- National Inst. of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan); CREST, Kawaguchi (Japan). Japan Science and Technology Agency
- CREST, Kawaguchi (Japan). Japan Science and Technology Agency; National Inst. of Advanced Industrial Science and Technology (AIST), Koriyama (Japan). Renewable Energy Research Center
- National Inst. of Advanced Industrial Science and Technology (AIST), Tsukuba (Japan); CREST, Kawaguchi (Japan). Japan Science and Technology Agency; National Inst. of Advanced Industrial Science and Technology (AIST), Koriyama (Japan). Renewable Energy Research Center
In a Cp*Ir complex with a bidentate pyridyl-imidazoline ligand achieved the evolution of 1.02 m3 of H2/CO2 gases by formic acid dehydrogenation without any additives or adjustments in the solution system. Furthermore, the pyridyl-imidazoline moieties provided the optimum pH to be 1.7, resulting in high activity and stability even at very acidic conditions.
- Research Organization:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- Grant/Contract Number:
- SC00112704
- OSTI ID:
- 1335388
- Report Number(s):
- BNL-111792-2016-JA; CSTAGD; R&D Project: CO026; KC0304030
- Journal Information:
- Catalysis Science and Technology, Vol. 6, Issue 4; ISSN 2044-4753
- Publisher:
- Royal Society of ChemistryCopyright Statement
- Country of Publication:
- United States
- Language:
- English
Cited by: 61 works
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