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Title: CO2 hydrogenation over oxide-supported PtCo catalysts: The role of the oxide support in determining the product selectivity

Journal Article · · Angewandte Chemie (International Edition)
 [1];  [2];  [1];  [1];  [3];  [2];  [1];  [4]
  1. Brookhaven National Lab. (BNL), Upton, NY (United States)
  2. Columbia Univ., New York, NY (United States)
  3. Chinese Academy of Science, Dalian (China)
  4. Brookhaven National Lab. (BNL), Upton, NY (United States); Columbia Univ., New York, NY (United States)
+ Show Author Affiliations

Abstract By simply changing the oxide support, the selectivity of a metal–oxide catalysts can be tuned. For the CO 2 hydrogenation over PtCo bimetallic catalysts supported on different reducible oxides (CeO 2 , ZrO 2 , and TiO 2 ), replacing a TiO 2 support by CeO 2 or ZrO 2 selectively strengthens the binding of C,O‐bound and O‐bound species at the PtCo–oxide interface, leading to a different product selectivity. These results reveal mechanistic insights into how the catalytic performance of metal–oxide catalysts can be fine‐tuned.

Research Organization:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
SC00112704
OSTI ID:
1333197
Alternate ID(s):
OSTI ID: 1401667
Report Number(s):
BNL-113193-2016-JA; R&D Project: CO035; KC0302010
Journal Information:
Angewandte Chemie (International Edition), Vol. 55, Issue 28; ISSN 1433-7851
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 220 works
Citation information provided by
Web of Science

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Layered Double Hydroxide-Based Catalysts: Recent Advances in Preparation, Structure, and Applications journal September 2018
Tailoring Surface Frustrated Lewis Pairs of In 2 O 3− x (OH) y for Gas-Phase Heterogeneous Photocatalytic Reduction of CO 2 by Isomorphous Substitution of In 3+ with Bi 3+ journal March 2018
MOFs-Based Heterogeneous Catalysts: New Opportunities for Energy-Related CO 2 Conversion journal October 2018
Tuning the Selectivity of Catalytic Carbon Dioxide Hydrogenation over Iridium/Cerium Oxide Catalysts with a Strong Metal-Support Interaction journal August 2017
Selective Hydrogenation of CO 2 to Ethanol over Cobalt Catalysts journal April 2018
Kopplung von Solarenergie und Wärmeenergie zur Kohlendioxidreduktion: Aktueller Stand und Perspektiven journal February 2020
Three‐Phase Photocatalysis for the Enhanced Selectivity and Activity of CO 2 Reduction on a Hydrophobic Surface journal September 2019
Controllable Conversion of CO 2 on Non‐Metallic Gold Clusters journal December 2019
Tuning the Selectivity of Catalytic Carbon Dioxide Hydrogenation over Iridium/Cerium Oxide Catalysts with a Strong Metal-Support Interaction journal August 2017
Selective Hydrogenation of CO 2 to Ethanol over Cobalt Catalysts journal April 2018
The Interplay between Structure and Product Selectivity of CO 2 Hydrogenation journal June 2019
Coupling of Solar Energy and Thermal Energy for Carbon Dioxide Reduction: Status and Prospects journal February 2020
Three‐Phase Photocatalysis for the Enhanced Selectivity and Activity of CO 2 Reduction on a Hydrophobic Surface journal September 2019
Controllable Conversion of CO 2 on Non‐Metallic Gold Clusters journal January 2020
Operando Spectroscopic Evidence of the Induced Effect of Residual Species in the Reaction Intermediates during CO 2 Hydrogenation over Ruthenium Nanoparticles journal March 2019
Influence of Coordination Environment of Anchored Single‐Site Cobalt Catalyst on CO 2 Hydrogenation journal December 2019
Unravelling the Promotional Effect of La 2 O 3 in Pt/La‐TiO 2 Catalysts for CO 2 Hydrogenation journal November 2019
Potassium-Promoted Molybdenum Carbide as a Highly Active and Selective Catalyst for CO 2 Conversion to CO journal May 2017
Carbon Capture and Utilization Update journal March 2017
Sequential Oxygen Reduction and Adsorption for Carbon Dioxide Purification for Flue Gas Applications journal March 2019
Highly Efficient Carbon Dioxide Hydrogenation to Methanol Catalyzed by Zigzag Platinum-Cobalt Nanowires journal April 2017
Promoting the Direct H 2 O 2 Generation Catalysis by Using Hollow Pd-Sn Intermetallic Nanoparticles journal March 2018
Evaluating differences in the active-site electronics of supported Au nanoparticle catalysts using Hammett and DFT studies journal January 2018
Controlling selectivities in CO2 reduction through mechanistic understanding journal September 2017
Understanding carbon dioxide activation and carbon–carbon coupling over nickel journal November 2019
CO2 hydrogenation to high-value products via heterogeneous catalysis journal December 2019
Chemically and electrochemically catalysed conversion of CO2 to CO with follow-up utilization to value-added chemicals journal April 2018
The renaissance of the Sabatier reaction and its applications on Earth and in space journal March 2019
Selective hydrogenation of CO 2 to methanol catalyzed by Cu supported on rod-like La 2 O 2 CO 3 journal January 2018
Insight into the structure and morphology of Ru n clusters on Co(111) and Co(311) surfaces journal January 2018
Hydroxyl-mediated ethanol selectivity of CO 2 hydrogenation journal January 2019
Interface engineering of palladium and zinc oxide nanorods with strong metal–support interactions for enhanced hydrogen production from base-free formaldehyde solution journal January 2019
A redox interaction-engaged strategy for multicomponent nanomaterials journal January 2020
A mini review of in situ near-ambient pressure XPS studies on non-noble, late transition metal catalysts journal January 2019
Active sites for tandem reactions of CO 2 reduction and ethane dehydrogenation journal July 2018
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Recent In Situ/Operando Spectroscopy Studies of Heterogeneous Catalysis with Reducible Metal Oxides as Supports journal May 2019
Sequential Oxygen Reduction and Adsorption for Carbon Dioxide Purification for Flue Gas Applications journal March 2019

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