Enhanced structural stability and photo responsiveness of CH3NH3SnI3 perovskite via pressure-induced amorphization and recrystallization

Lu, Xujie; Wang, Yonggang; Stoumpos, Constantinos C.; Hu, Qingyang; Guo, Xiaofeng; Chen, Haijie; Yang, Liuxiang; Smith, Jesse S.; Yang, Wenge; Zhao, Yusheng; Xu, Hongwu; Kanatzidis, Mercouri G.; Jia, Quanxi

doi:10.1002/adma.201600771

Title: Enhanced structural stability and photo responsiveness of CH₃NH₃SnI₃ perovskite via pressure-induced amorphization and recrystallization

Journal Article · Sat Oct 01 00:00:00 EDT 2016 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201600771· OSTI ID:1331268

Lu, Xujie ^[1]; Wang, Yonggang ^[2]; Stoumpos, Constantinos C. ^[3]; Hu, Qingyang ^[4]; Guo, Xiaofeng ^[1]; Chen, Haijie ^[3]; Yang, Liuxiang ^[5]; Smith, Jesse S. ^[5]; Yang, Wenge ^[4]; Zhao, Yusheng ^[6]; Xu, Hongwu ^[1]; Kanatzidis, Mercouri G. ^[3]; Jia, Quanxi ^[1]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
Univ. of Nevada, Las Vegas, NV (United States); Carnegie Institution of Washington, Argonne, IL (United States)
Northwestern Univ., Evanston, IL (United States)
Carnegie Institution of Washington, Argonne, IL (United States); Center for High Pressure Science and Technology Advanced Research (HPSTAR), Shanghai (China)
Carnegie Institution of Washington, Argonne, IL (United States)
Univ. of Nevada, Las Vegas, NV (United States); Southern Univ. of Science and Technology, Shenzhen (China)

An organic–inorganic halide CH₃NH₃SnI₃ perovskite with significantly improved structural stability is obtained via pressure-induced amorphization and recrystallization. In situ high-pressure resistance measurements reveal an increased electrical conductivity by 300% in the pressure-treated perovskite. Photocurrent measurements also reveal a substantial enhancement in visible-light responsiveness. In conclusion, the mechanism underlying the enhanced properties is shown to be associated with the pressure-induced structural modification.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC52-06NA25396

OSTI ID:: 1331268

Report Number(s):: LA-UR-15-29677

Journal Information:: Advanced Materials, Vol. 28, Issue 39; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 147 works

Citation information provided by
Web of Science

References (51)

Metal-halide perovskites for photovoltaic and light-emitting devices Stranks, Samuel D.; Snaith, Henry J. Nature Nanotechnology, Vol. 10, Issue 5 https://doi.org/10.1038/nnano.2015.90	journal	May 2015
Pressure-Induced Amorphization in Single-Crystal Ta ₂ O ₅ Nanowires: A Kinetic Mechanism and Improved Electrical Conductivity Lü, Xujie; Hu, Qingyang; Yang, Wenge Journal of the American Chemical Society, Vol. 135, Issue 37 https://doi.org/10.1021/ja407108u	journal	September 2013
The Renaissance of Halide Perovskites and Their Evolution as Emerging Semiconductors Stoumpos, Constantinos C.; Kanatzidis, Mercouri G. Accounts of Chemical Research, Vol. 48, Issue 10 https://doi.org/10.1021/acs.accounts.5b00229	journal	September 2015
Re-emerging superconductivity at 48 kelvin in iron chalcogenides Sun, Liling; Chen, Xiao-Jia; Guo, Jing Nature, Vol. 483, Issue 7387 https://doi.org/10.1038/nature10813	journal	February 2012
The emergence of perovskite solar cells Green, Martin A.; Ho-Baillie, Anita; Snaith, Henry J. Nature Photonics, Vol. 8, Issue 7, p. 506-514 https://doi.org/10.1038/nphoton.2014.134	journal	July 2014
Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals Shi, D.; Adinolfi, V.; Comin, R. Science, Vol. 347, Issue 6221 https://doi.org/10.1126/science.aaa2725	journal	January 2015
Improved performance and stability of perovskite solar cells by crystal crosslinking with alkylphosphonic acid ω-ammonium chlorides Li, Xiong; Ibrahim Dar, M.; Yi, Chenyi Nature Chemistry, Vol. 7, Issue 9 https://doi.org/10.1038/nchem.2324	journal	August 2015
Direct measurement of the exciton binding energy and effective masses for charge carriers in organic–inorganic tri-halide perovskites Miyata, Atsuhiko; Mitioglu, Anatolie; Plochocka, Paulina Nature Physics, Vol. 11, Issue 7 https://doi.org/10.1038/nphys3357	journal	June 2015
Interface engineering of highly efficient perovskite solar cells Zhou, H.; Chen, Q.; Li, G. Science, Vol. 345, Issue 6196 https://doi.org/10.1126/science.1254050	journal	July 2014
Finite Elastic Strain of Cubic Crystals Birch, Francis Physical Review, Vol. 71, Issue 11 https://doi.org/10.1103/PhysRev.71.809	journal	June 1947
High-performance photovoltaic perovskite layers fabricated through intramolecular exchange Yang, W. S.; Noh, J. H.; Jeon, N. J. Science, Vol. 348, Issue 6240 https://doi.org/10.1126/science.aaa9272	journal	May 2015
CH ₃ NH ₃ PbI ₃ Perovskite/Fullerene Planar-Heterojunction Hybrid Solar Cells Jeng, Jun-Yuan; Chiang, Yi-Fang; Lee, Mu-Huan Advanced Materials, Vol. 25, Issue 27 https://doi.org/10.1002/adma.201301327	journal	June 2013
Pressure Dependence of the Elastic Constants of SrTiO ₃ Beattie, A. G.; Samara, G. A. Journal of Applied Physics, Vol. 42, Issue 6 https://doi.org/10.1063/1.1660551	journal	May 1971
Halide Perovskites: Poor Man's High-Performance Semiconductors Stoumpos, Constantinos C.; Kanatzidis, Mercouri G. Advanced Materials, Vol. 28, Issue 28 https://doi.org/10.1002/adma.201600265	journal	May 2016
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells Jeon, Nam Joong; Noh, Jun Hong; Kim, Young Chan Nature Materials, Vol. 13, Issue 9, p. 897-903 https://doi.org/10.1038/nmat4014	journal	July 2014
Solar cell efficiency tables (Version 45): Solar cell efficiency tables Green, Martin A.; Emery, Keith; Hishikawa, Yoshihiro Progress in Photovoltaics: Research and Applications, Vol. 23, Issue 1 https://doi.org/10.1002/pip.2573	journal	December 2014
Current progress and future perspectives for organic/inorganic perovskite solar cells Boix, Pablo P.; Nonomura, Kazuteru; Mathews, Nripan Materials Today, Vol. 17, Issue 1 https://doi.org/10.1016/j.mattod.2013.12.002	journal	January 2014
Formability of ABX ₃ ( X = F, Cl, Br, I) halide perovskites Li, Chonghea; Lu, Xionggang; Ding, Weizhong Acta Crystallographica Section B Structural Science, Vol. 64, Issue 6 https://doi.org/10.1107/S0108768108032734	journal	November 2008
Semiconducting Tin and Lead Iodide Perovskites with Organic Cations: Phase Transitions, High Mobilities, and Near-Infrared Photoluminescent Properties Stoumpos, Constantinos C.; Malliakas, Christos D.; Kanatzidis, Mercouri G. Inorganic Chemistry, Vol. 52, Issue 15, p. 9019-9038 https://doi.org/10.1021/ic401215x	journal	July 2013
Nanotwinned diamond with unprecedented hardness and stability Huang, Quan; Yu, Dongli; Xu, Bo Nature, Vol. 510, Issue 7504 https://doi.org/10.1038/nature13381	journal	June 2014
The light and shade of perovskite solar cells Grätzel, Michael Nature Materials, Vol. 13, Issue 9 https://doi.org/10.1038/nmat4065	journal	August 2014
Methylamine-Gas-Induced Defect-Healing Behavior of CH ₃ NH ₃ PbI ₃ Thin Films for Perovskite Solar Cells Zhou, Zhongmin; Wang, Zaiwei; Zhou, Yuanyuan Angewandte Chemie International Edition, Vol. 54, Issue 33 https://doi.org/10.1002/anie.201504379	journal	June 2015
Strength and texture of Pt compressed to 63 GPa Dorfman, Susannah M.; Shieh, Sean R.; Duffy, Thomas S. Journal of Applied Physics, Vol. 117, Issue 6 https://doi.org/10.1063/1.4907866	journal	February 2015
Transparent dense sodium Ma, Yanming; Eremets, Mikhail; Oganov, Artem R. Nature, Vol. 458, Issue 7235 https://doi.org/10.1038/nature07786	journal	March 2009
Pressure-Induced Phase Transformation, Reversible Amorphization, and Anomalous Visible Light Response in Organolead Bromide Perovskite Wang, Yonggang; Lü, Xujie; Yang, Wenge Journal of the American Chemical Society, Vol. 137, Issue 34 https://doi.org/10.1021/jacs.5b06346	journal	August 2015
The Raman Spectrum of the CH ₃ NH ₃ PbI ₃ Hybrid Perovskite: Interplay of Theory and Experiment Quarti, Claudio; Grancini, Giulia; Mosconi, Edoardo The Journal of Physical Chemistry Letters, Vol. 5, Issue 2 https://doi.org/10.1021/jz402589q	journal	December 2013
Ultrahard nanotwinned cubic boron nitride Tian, Yongjun; Xu, Bo; Yu, Dongli Nature, Vol. 493, Issue 7432 https://doi.org/10.1038/nature11728	journal	January 2013
General Rules for Predicting Phase Transitions in Perovskites due to Octahedral Tilting Angel, R. J.; Zhao, J.; Ross, N. L. Physical Review Letters, Vol. 95, Issue 2 https://doi.org/10.1103/PhysRevLett.95.025503	journal	July 2005
Creation of Nanostuctures by Extreme Conditions: High-Pressure Synthesis of Ultrahard Nanocrystalline Cubic Boron Nitride Solozhenko, Vladimir L.; Kurakevych, Oleksandr O.; Le Godec, Yann Advanced Materials, Vol. 24, Issue 12 https://doi.org/10.1002/adma.201104361	journal	February 2012
Planar Heterojunction Perovskite Solar Cells via Vapor-Assisted Solution Process Chen, Qi; Zhou, Huanping; Hong, Ziruo Journal of the American Chemical Society, Vol. 136, Issue 2, p. 622-625 https://doi.org/10.1021/ja411509g	journal	December 2013
Long-Range Topological Order in Metallic Glass Zeng, Q.; Sheng, H.; Ding, Y. Science, Vol. 332, Issue 6036 https://doi.org/10.1126/science.1200324	journal	June 2011
Pressure-induced phase transitions and templating effect in three-dimensional organic-inorganic hybrid perovskites Lee, Yongjae; Mitzi, David B.; Barnes, Paris W. Physical Review B, Vol. 68, Issue 2 https://doi.org/10.1103/PhysRevB.68.020103	journal	July 2003
Perovskite Solid Solutions along the NaNbO ₃ −SrTiO ₃ Join: Phase Transitions, Formation Enthalpies, and Implications for General Perovskite Energetics Xu, Hongwu; Navrotsky, Alexandra; Su, Yali Chemistry of Materials, Vol. 17, Issue 7 https://doi.org/10.1021/cm047785i	journal	April 2005
Sequential deposition as a route to high-performance perovskite-sensitized solar cells Burschka, Julian; Pellet, Norman; Moon, Soo-Jin Nature, Vol. 499, Issue 7458, p. 316-319 https://doi.org/10.1038/nature12340	journal	July 2013
Pressure Response of an Organic−Inorganic Perovskite: Methylammonium Lead Bromide Swainson, I. P.; Tucker, M. G.; Wilson, D. J. Chemistry of Materials, Vol. 19, Issue 10 https://doi.org/10.1021/cm0621601	journal	May 2007
Solvent-Mediated Crystallization of CH₃NH₃SnI₃ Films for Heterojunction Depleted Perovskite Solar Cells Hao, Feng; Stoumpos, Constantinos C.; Guo, Peijun Journal of the American Chemical Society, Vol. 137, Issue 35, p. 11445-11452 https://doi.org/10.1021/jacs.5b06658	journal	August 2015
In situ observation of texture development in olivine, ringwoodite, magnesiowüstite and silicate perovskite at high pressure Wenk, H. -R.; Lonardeli, I.; Pehl, J. Earth and Planetary Science Letters, Vol. 226, Issue 3-4 https://doi.org/10.1016/j.epsl.2004.07.033	journal	October 2004
Efficient planar heterojunction perovskite solar cells by vapour deposition Liu, Mingzhen; Johnston, Michael B.; Snaith, Henry J. Nature, Vol. 501, Issue 7467, p. 395-398 https://doi.org/10.1038/nature12509	journal	September 2013
Enhanced Electron Transport in Nb-Doped TiO ₂ Nanoparticles via Pressure-Induced Phase Transitions Lü, Xujie; Yang, Wenge; Quan, Zewei Journal of the American Chemical Society, Vol. 136, Issue 1 https://doi.org/10.1021/ja410810w	journal	December 2013
Size-Dependent Pressure-Induced Amorphization in Nanoscale ${TiO}_{2}$ Swamy, Varghese; Kuznetsov, Alexei; Dubrovinsky, Leonid S. Physical Review Letters, Vol. 96, Issue 13 https://doi.org/10.1103/PhysRevLett.96.135702	journal	April 2006
Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites Lee, M. M.; Teuscher, J.; Miyasaka, T. Science, Vol. 338, Issue 6107, p. 643-647 https://doi.org/10.1126/science.1228604	journal	October 2012
Lead-free solid-state organic–inorganic halide perovskite solar cells Hao, Feng; Stoumpos, Constantinos C.; Cao, Duyen Hanh Nature Photonics, Vol. 8, Issue 6 https://doi.org/10.1038/nphoton.2014.82	journal	May 2014
Under the spotlight: The organic–inorganic hybrid halide perovskite for optoelectronic applications Chen, Qi; De Marco, Nicholas; Yang, Yang (Michael) Nano Today, Vol. 10, Issue 3 https://doi.org/10.1016/j.nantod.2015.04.009	journal	June 2015
Compositional engineering of perovskite materials for high-performance solar cells Jeon, Nam Joong; Noh, Jun Hong; Yang, Woon Seok Nature, Vol. 517, Issue 7535 https://doi.org/10.1038/nature14133	journal	January 2015
Material Innovation in Advancing Organometal Halide Perovskite Functionality Zheng, Fan; Saldana-Greco, Diomedes; Liu, Shi The Journal of Physical Chemistry Letters, Vol. 6, Issue 23 https://doi.org/10.1021/acs.jpclett.5b01830	journal	November 2015
Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9% Kim, Hui-Seon; Lee, Chang-Ryul; Im, Jeong-Hyeok Scientific Reports, Vol. 2, Issue 1 https://doi.org/10.1038/srep00591	journal	August 2012
Pressure Response of an Organic—Inorganic Perovskite: Methylammonium Lead Bromide. Swainson, I. P.; Tucker, M. G.; Wilson, D. J. ChemInform, Vol. 38, Issue 32 https://doi.org/10.1002/chin.200732007	journal	August 2007
Direct measurement of the exciton binding energy and effective masses for charge carriers in organic–inorganic tri-halide perovskites Miyata, A.; Mitioglu, A.; Plochocka, P. Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.38431	text	January 2015
Methylamine-Gas-Induced Defect-Healing Behavior of CH ₃ NH ₃ PbI ₃ Thin Films for Perovskite Solar Cells Zhou, Zhongmin; Wang, Zaiwei; Zhou, Yuanyuan Angewandte Chemie, Vol. 127, Issue 33 https://doi.org/10.1002/ange.201504379	journal	June 2015
Transparent dense sodium Ma, Y.; Eremets, M. I.; Oganov, A. R. arXiv https://doi.org/10.48550/arxiv.0911.3190	text	January 2009
Direct Measurement of the Exciton Binding Energy and Effective Masses for Charge carriers in an Organic-Inorganic Tri-halide Perovskite Miyata, Atsuhiko; Mitioglu, Anatolie; Plochocka, Paulina arXiv https://doi.org/10.48550/arxiv.1504.07025	text	January 2015

Cited By (28)

Efficient and Ambient-Air-Stable Solar Cell with Highly Oriented 2D@3D Perovskites Ye, Tao; Bruno, Annalisa; Han, Guifang Advanced Functional Materials, Vol. 28, Issue 30 https://doi.org/10.1002/adfm.201801654	journal	May 2018
Lead-Free Organic-Inorganic Hybrid Perovskites for Photovoltaic Applications: Recent Advances and Perspectives Shi, Zejiao; Guo, Jia; Chen, Yonghua Advanced Materials, Vol. 29, Issue 16 https://doi.org/10.1002/adma.201605005	journal	February 2017
Nanocube Superlattices of Cesium Lead Bromide Perovskites and Pressure-Induced Phase Transformations at Atomic and Mesoscale Levels Nagaoka, Yasutaka; Hills-Kimball, Katie; Tan, Rui Advanced Materials, Vol. 29, Issue 18 https://doi.org/10.1002/adma.201606666	journal	March 2017
Large Band Gap Narrowing and Prolonged Carrier Lifetime of (C ₄ H ₉ NH ₃ ) ₂ PbI ₄ under High Pressure Yuan, Ye; Liu, Xiao‐Fei; Ma, Xuedan Advanced Science https://doi.org/10.1002/advs.201900240	journal	June 2019
Pressure‐Induced Structural Evolution and Bandgap Optimization of Lead‐Free Halide Double Perovskite (NH ₄ ) ₂ SeBr ₆ Wang, Lingrui; Yao, Panpan; Wang, Fei Advanced Science, Vol. 7, Issue 6 https://doi.org/10.1002/advs.201902900	journal	March 2020
Pressure-Induced Emission Enhancement, Band-Gap Narrowing, and Metallization of Halide Perovskite Cs ₃ Bi ₂ I ₉ Zhang, Long; Liu, Chunming; Wang, Lingrui Angewandte Chemie, Vol. 130, Issue 35 https://doi.org/10.1002/ange.201804310	journal	July 2018
High-Pressure Band-Gap Engineering in Lead-Free Cs ₂ AgBiBr ₆ Double Perovskite Li, Qian; Wang, Yonggang; Pan, Weicheng Angewandte Chemie International Edition, Vol. 56, Issue 50 https://doi.org/10.1002/anie.201708684	journal	November 2017
High‐Pressure Band‐Gap Engineering and Metallization in the Perovskite Derivative Cs ₃ Sb ₂ I ₉ Wu, Lianwei; Dong, Zhiying; Zhang, Long ChemSusChem, Vol. 12, Issue 17 https://doi.org/10.1002/cssc.201901388	journal	July 2019
0D Cs ₃ Cu ₂ X ₅ (X = I, Br, and Cl) Nanocrystals: Colloidal Syntheses and Optical Properties Luo, Zhishan; Li, Qian; Zhang, Liming Small, Vol. 16, Issue 3 https://doi.org/10.1002/smll.201905226	journal	December 2019
Performance enhancement of perovskite solar cells using a La-doped BaSnO ₃ electron transport layer Zhu, Liangzheng; Ye, Jiajiu; Zhang, Xuhui Journal of Materials Chemistry A, Vol. 5, Issue 7 https://doi.org/10.1039/c6ta09689a	journal	January 2017
A computational approach to interface engineering of lead-free CH ₃ NH ₃ SnI ₃ highly-efficient perovskite solar cells Lazemi, Masoud; Asgharizadeh, Saeid; Bellucci, Stefano Physical Chemistry Chemical Physics, Vol. 20, Issue 40 https://doi.org/10.1039/c8cp03660h	journal	January 2018
Pressure-induced effects in the inorganic halide perovskite CsGeI ₃ Liu, Diwen; Li, Qiaohong; Jing, Huijuan RSC Advances, Vol. 9, Issue 6 https://doi.org/10.1039/c8ra10251a	journal	January 2019
Building bridges between halide perovskite nanocrystals and thin-film solar cells Yang, Hanjun; Zhang, Yi; Hills-Kimball, Katie Sustainable Energy & Fuels, Vol. 2, Issue 11 https://doi.org/10.1039/c8se00315g	journal	January 2018
Giant enhancements in electronic transport and photoelectric properties of bismuth oxysulfide by pressure-driven 2D–3D structural reconstruction Zhang, Ganghua; Zhang, Qian; Hu, Qingyang Journal of Materials Chemistry A, Vol. 7, Issue 8 https://doi.org/10.1039/c8ta11168e	journal	January 2019
Emission enhancement and bandgap retention of a two-dimensional mixed cation lead halide perovskite under high pressure Chen, Yaping; Fu, Ruijing; Wang, Lingrui Journal of Materials Chemistry A, Vol. 7, Issue 11 https://doi.org/10.1039/c8ta11992a	journal	January 2019
Mechanical properties of the ferroelectric metal-free perovskite [MDABCO](NH ₄ )I ₃ Ehrenreich, Michael G.; Zeng, Zhixin; Burger, Stefan Chemical Communications, Vol. 55, Issue 27 https://doi.org/10.1039/c9cc00580c	journal	January 2019
Tunable photoluminescence and an enhanced photoelectric response of Mn ²⁺ -doped CsPbCl ₃ perovskite nanocrystals via pressure-induced structure evolution Zhang, Junkai; Ji, Sihang; Ma, Yanzhang Nanoscale, Vol. 11, Issue 24 https://doi.org/10.1039/c9nr03045j	journal	January 2019
Bandgap engineering in two-dimensional halide perovskite Cs ₃ Sb ₂ I ₉ nanocrystals under pressure Geng, Ting; Ma, Zhiwei; Chen, Yaping Nanoscale, Vol. 12, Issue 3 https://doi.org/10.1039/c9nr09533k	journal	January 2020
Pressure-induced structural evolution, optical and electronic transitions of nontoxic organometal halide perovskite-based methylammonium tin chloride Wang, Lingrui; Ou, Tianji; Wang, Kai Applied Physics Letters, Vol. 111, Issue 23 https://doi.org/10.1063/1.5004186	journal	December 2017
Pressure effects on the inductive loop, mixed conduction, and photoresponsivity in formamidinium lead bromide perovskite Ou, Tianji; Ma, Xinjun; Yan, Huacai Applied Physics Letters, Vol. 113, Issue 26 https://doi.org/10.1063/1.5063394	journal	December 2018
Pressure responses of halide perovskites with various compositions, dimensionalities, and morphologies Li, Mei; Liu, Tianbiao; Wang, Yonggang Matter and Radiation at Extremes, Vol. 5, Issue 1 https://doi.org/10.1063/1.5133653	journal	January 2020
Isothermal pressure-derived metastable states in 2D hybrid perovskites showing enduring bandgap narrowing Liu, Gang; Gong, Jue; Kong, Lingping Proceedings of the National Academy of Sciences, Vol. 115, Issue 32 https://doi.org/10.1073/pnas.1809167115	journal	July 2018
Ytterbium-doped fiber laser passively mode locked by evanescent field interaction with CH ₃ NH ₃ SnI ₃ perovskite saturable absorber Bao, Xiaozhi; Mu, Haoran; Chen, Yao Journal of Physics D: Applied Physics, Vol. 51, Issue 37 https://doi.org/10.1088/1361-6463/aad71d	journal	August 2018
Pressure induced transformation and subsequent amorphization of monoclinic Nb ₂ O ₅ and its effect on optical properties Guan, Zhou; Li, Quanjun; Zhang, Huafang Journal of Physics: Condensed Matter, Vol. 31, Issue 10 https://doi.org/10.1088/1361-648x/aaf9bd	journal	January 2019
Ultrafast carrier dynamics in all-inorganic CsPbBr 3 perovskite across the pressure-induced phase transition Liu, Xiaochun; Han, Jianhui; Li, You Optics Express, Vol. 27, Issue 16 https://doi.org/10.1364/oe.27.00a995	journal	January 2019
Metal Halide Perovskite Single Crystals: From Growth Process to Application Li, Shuigen; Zhang, Chen; Song, Jiao-Jiao Crystals, Vol. 8, Issue 5 https://doi.org/10.3390/cryst8050220	journal	May 2018
High-Pressure Band-Gap Engineering in Lead-Free Cs ₂ AgBiBr ₆ Double Perovskite Li, Qian; Wang, Yonggang; Pan, Weicheng Angewandte Chemie, Vol. 129, Issue 50 https://doi.org/10.1002/ange.201708684	journal	November 2017
Pressure-Induced Emission Enhancement, Band-Gap Narrowing, and Metallization of Halide Perovskite Cs ₃ Bi ₂ I ₉ Zhang, Long; Liu, Chunming; Wang, Lingrui Angewandte Chemie International Edition, Vol. 57, Issue 35 https://doi.org/10.1002/anie.201804310	journal	July 2018

Similar Records

Solvent-Mediated Crystallization of CH₃NH₃SnI₃ Films for Heterojunction Depleted Perovskite Solar Cells

Journal Article · Thu Aug 27 00:00:00 EDT 2015 · Journal of the American Chemical Society · OSTI ID:1331268

Hao, Feng; Stoumpos, Constantinos C.; Guo, Peijun; +4 more

Lead free CH{sub 3}NH{sub 3}SnI{sub 3} perovskite thin-film with p-type semiconducting nature and metal-like conductivity

Journal Article · Mon Aug 15 00:00:00 EDT 2016 · AIP Advances · OSTI ID:1331268

Iefanova, Anastasiia; Adhikari, Nirmal; Dubey, Ashish; +2 more

Hall mobility in tin iodide perovskite CH{sub 3}NH{sub 3}SnI{sub 3}: Evidence for a doped semiconductor

Journal Article · Sun Sep 15 00:00:00 EDT 2013 · Journal of Solid State Chemistry · OSTI ID:1331268

Takahashi, Yukari; Hasegawa, Hiroyuki; Takahashi, Yukihiro; +1 more

Related Subjects

36 MATERIALS SCIENCE
Material Science
Solar cells
high pressure

Title: Enhanced structural stability and photo responsiveness of CH3NH3SnI3 perovskite via pressure-induced amorphization and recrystallization

Citation Formats

References (51)

Cited By (28)

Similar Records

Related Subjects

Title: Enhanced structural stability and photo responsiveness of CH₃NH₃SnI₃ perovskite via pressure-induced amorphization and recrystallization